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THE Hydrogen Thread pt 3 (merged)

Discussions of conventional and alternative energy production technologies.

Methane leaking to atmosphere

Postby baldwincng » Wed 20 Apr 2005, 07:43:10

Devil said:

You still ignore the FACT that NG is the worst GHG of the ordinary fuel sources and is already the most rapidly increasing GHG in the atmosphere. If we were to follow your tenets, it will overtake CO2 in 50 years, by which time we'll probably be frying, anyway.

I do not ignore the fact that methane is a bad gas as far as global warming is concerned - around 20 times worse than CO2. Thats why I want to set fire to the methane that leaks out of landfill sites, burning it in the engines of cars buses and trucks so that it does not leak out. It's not obvious what else you can do to land-fill methane to reduce its global warming impact, other than setting fire to it. Any suggestions?

Methane levels in the atmosphere may be rising but the contribution of natural gas vehicles to that is negligible....I can easily explain why.

There are 15 million cows in Germany, giving out around 800,000 tonnes of methane per year.

There are around 15 OEM produced cars on sale in Germany that meet the EuroIV emissions standard which is very tight on methane emissions (0.2g of methane per km travelled).

I've been told that if all 42.8 Million cars in Germany ran on CNG (at Euro IV), then that would pass 800,000 tonnes of methane into the atmosphere every 8.9 years.

I don't need to check the calculation to know that NGVs can help to reduce the levels of methane in the atmosphere because of landfill emissions (such gas which is not easily injected into gas mains because of issues related to its burning characteristics but it is very easily burnt in car engines). Once CNG vehicles are widespread, the landfill problem is solved.

CNG vehicles can save the planet (at least for a bit)
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Postby Devil » Wed 20 Apr 2005, 08:36:18

Sometimes I despair when guys like you are so blinkered that you only see the facts that suit your arguments. :(

Landfills: $this->bbcode_second_pass_quote('', 'n')ot later than 15 years after the date laid down in Article 18(1), biodegradable municipal waste going to landfills must be reduced to 35 % of the total amount (by weight) of biodegradable municipal waste produced in 1995 or the latest year before 1995 for which standardised Eurostat data is available.


This quote from the EU Council Directive 1999/31/EC of 26 April 1999 on the landfill of waste, Art. 5.2 (c) shows that 65% of your methane source from landfills will have dried up in the EU in the next decade. What then?

In any case, methane from landfills represent only 7.55% of the total emissions, worldwide, according to Tetlow-Smith. Gas drilling and distribution is more. And, if CH4 were widely used for vehicles, not only would emissions of this increase, but CO2 emissions would hardly decrease, bearing in mind that every kg of CH4 that is burned will produce nearly 2.5 kg of CO2 and that assumes perfect combustion.

However, you seem to think the enteric fermentation in ruminants and other herbivores is important, and so it is, roughly twice that of landfills. But you would have to nuke the Serengeti, Masai Mara and other E. and S. African grasslands to make a significant reduction. While you're about it, drain all the natural wetlands and rice paddies in the world, and that will halve all the CH4 emissions (except those from all the rotting human and animal cadavers).

I'm sorry, but your desire to sell NG is blinding you from the holistic view that it is not a desirable fuel.
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What to do with methane from rotting plants etc

Postby baldwincng » Wed 20 Apr 2005, 09:21:56

Devil. $this->bbcode_second_pass_quote('', 'S')ometimes I despair when guys like you are so blinkered that you only see the facts that suit your arguments


Me too. You still don't get it do you? I'll have another go.

One of the main reasons that the amount of bio-degradable waste will have fallen by 65% is that local authorities will have to separate out the bio-degradable waste before it goes to landfill. If you are in Sweden or Lille, you will take this green waste and make it into bio-gas to power vehicles!! Take a look at this link that tells about the 120 bio-gas buses in Lille:

http://www.trendsetter-europe.org/index.php?ID=962

From this website:
$this->bbcode_second_pass_quote('', 'T')he authority will gradually increase the use of biogas, utilising biogas produced in the planned plant for fermenting organic waste and a new bus depot adjacent to the waste treatment plant.


Clearly, this is done to comply with the EU Dirtective you refer to.

What do you think they do with the green material separated before it gets to landfill? Maybe you think that they'll keep it in a fridge so it doesn't decompose perhaps?

If you have a better and greener idea than setting fire to it in vehicle engines lets hear it.

It is very important that we all take a holistic view of emissions of greenhouse gases and we take time to think about it properly and consider all the facts. Just because an EU Directive says methane emissions may be less of a problem at one place does not mean that these emissions have mysterously vanished. Some people will be fooled into believing this, I'm not one of them.
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Postby Devil » Wed 20 Apr 2005, 10:07:37

They will probably do as they are already doing in many towns in Switzerland: incinerating it is thermal power stations. This provides up to about 10% of the electricity requirements of the catchment area and also provides a means of disposing of non-compostable organic waste, such as the plastic bags that it is collected in. This is proven technology. In Lausanne and Zurich, the waste heat is used to provide all the megalitres of hot water (and the central heating in winter) for the Cantonal University Hospitals and some other neighbouring buildings. The only waste going to landfill is the ash.

I'll grant you that the incinerators are equipped with scrubbers and precipitators to remove any toxic or otherwise undesirable elements in the flue gases and this is relatively costly, but the electricity generated is sold and is profitable at standard rates. I forget the exact figure, but the total generating capacity from household waste in the country is somewhere near 250 MW the last time I looked, and this is not negligible.
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Swiss efforts to save the planet

Postby baldwincng » Wed 20 Apr 2005, 16:25:03

I think Switzerland is great when it comes to the environment, they are really making an efort to introduce CNG and are aligning it with their biogas programme too.

Take a look at www.biogas.ch to see what is happening in relation to biogas

The Swiss Gas & Water Association (SVGW) has ambitious plans for their NGV developments, part of which will be motivated by a change in the Swiss fuel tax regime for natural gas that is anticipated by 2007. Currently there are 59 CNG buses on Swiss roads, 299 light commercial vehicles and 856 natural gas passenger cars. Fifty-one fuelling stations are open publicly to support the planned growth, with another 20 stations planned to be constructed this year.

Biogas, which is injected into the natural gas grid currently is untaxed by the Swiss authorities, however, natural gas continues to be taxed at a higher rate than either diesel or gasoline. But the Swiss gas and NGV industries have been lobbying to change that and anticipate that a tax reduction will be awarded for natural gas, although not before 2007. This should help spur the market, coupled with NGV product entries from Germany (the Mercedes E2000 NGT), from Fiat, with a range of passenger cars (Multipla, Doblo, Punto), and Opel (Astra and Zafira).

The plans, according to SVGW, are to see a steady growth of NGVs between now and 2010, when they are targeting 30,000 NGVs of various types. The growth plan shows a steady rise: 2000 NGVs by the end of 2005; 3500 by the end of 2006; 7000 by the end of 2007; 12,000 by the end of 2008; and 20,000 by the end of 2009. Given the strength of the current fuelling infrastructure, these targets certainly would be achievable with the right mixture of government and industry support. Continued use of biogas also is planned, along with natural gas, making the Swiss program one that intends to overcome the 'chicken and egg'.
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Postby Andy » Fri 22 Apr 2005, 15:48:24

Baldwin

I think promoting NGV vehicles is a waste of time. Remember, we want to utilize fuels with absolute efficiency. Now, A NG engine's thermal efficiency is about the same as the best Otto cycle engines (i.e our plain old gasoline engines) getting about 37 - 38%.

We can use biogas mixed with natural gas in a combined cycle power plant (in the future in SOFC/turbine power plants) at > 50% heat to electricity efficiency. It is better to pipe the natural gas to the power plant or use it in a cogeneration mode in stationary facilities, home etc. and get much higher energy utilization per btu of available gas.

Wasting it in ICE powered vehicles does not make sense. There is also the problem of short range, storage tank weight etc.
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Use of natural gas

Postby baldwincng » Sat 23 Apr 2005, 02:55:15

Andy

I have responded to your comments on the CNG thread and partially agree with you - certainly making hydrogen and gasoline from natural gas are both incredibly inefficient processes and should be illegal.

There are no significant issues with CNG as a vehicle fuel. Trucks in the UK can now run 500 miles between fills and modern tanks are not made of steel but composite materials.

CNG gives lower overall CO2 emissions (well to wheel, taking account any methane losses), much lower NOX and particulates, quieter engines, keeps oil back for premium uses.

I have seen the future, its the Honda Civic CNG (+ hybrid version) http://automobiles.honda.com/models/mod ... +GX&bhcp=1
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Hyrogen as energy source

Postby amorando » Fri 29 Apr 2005, 10:25:39

I am been befuddled over hydrogen because most of it seemed to eminate from using fossil fuels, but recently I read of the possibility of getting hydrogen from bacteria degradation of waste or rotting organic materials. I don't know the details of this, whether these are particular bacteria, if the degradation needs to be done anearobically or what, but this is the kind of hydrogen sourcing we need.
It looks to me like much more experimentation will have to be done before we know if hydrogen will be the main replacement of petroleum.
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Re: Hyrogen as energy source

Postby Doly » Fri 29 Apr 2005, 10:40:02

$this->bbcode_second_pass_quote('amorando', 'I') am been befuddled over hydrogen because most of it seemed to eminate from using fossil fuels, but recently I read of the possibility of getting hydrogen from bacteria degradation of waste or rotting organic materials. I don't know the details of this, whether these are particular bacteria, if the degradation needs to be done anearobically or what, but this is the kind of hydrogen sourcing we need.


They are specific bacteria, genetically engineered, and the production of hydrogen is too low to be usable. But they are working on it.
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Re: Hyrogen as energy source

Postby BiGG » Fri 29 Apr 2005, 13:37:59

$this->bbcode_second_pass_quote('Doly', '
')
They are specific bacteria, genetically engineered, and the production of hydrogen is too low to be usable. But they are working on it.


amorando, Doly,

Did you see this information I posted in another thread on this subject? Looks pretty exciting!


Microbial Fuel Cell artical from Science Daily

Quotes from the artical:

Using a new electrically-assisted microbial fuel cell (MFC) that does not require oxygen …

……..first process that enables bacteria to coax four times as much hydrogen directly out of biomass than can be generated typically by fermentation alone

………process is not limited to using only carbohydrate-based biomass for hydrogen production like conventional fermentation processes. We can theoretically use our MFC to obtain high yields of hydrogen from any biodegradable, dissolved, organic matter -- human, agricultural or industrial wastewater, for example -- and simultaneously clean the wastewater.

"Basically, we use the same microbial fuel cell we developed to clean wastewater and produce electricity. However, to produce hydrogen ……..

Logan adds, "This new process demonstrates, for the first time, that there is real potential to capture hydrogen for fuel from renewable sources for clean transportation."


Check out Ion Power Inc. for more on this like: Scientists at Ion Power together with Dr Bruce Logan at Penn State, have invented a new way to adapt a Microbial Fuel Cell (MFC) to coax the microbes to generate hydrogen instead of electricity from biomass ...
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275-Megawatt Coal-to-Hydrogen Plant!

Postby BiGG » Wed 11 May 2005, 09:34:12

Big news for Coal-to-Hydrogen Production! Very Cool,!

275 Megawatt Coal-to-Hydrogen Plant

PITTSBURGH — Taking a step closer toward its vision of ultraclean, highly efficient power generation, the U.S. Department of Energy (DOE) will collaborate with a Colorado firm on a $15 million advanced research project to further develop coal-to-hydrogen production technology supporting DOE’s zero-emissions FutureGen plant of tomorrow.

Eltron Research Inc., of Boulder Colo., will conduct scale-up and advanced research on metal, alloy, or ceramic-metal membranes to separate hydrogen from carbon dioxide in a stream of synthetic gas produced in coal gasification. Based in part on materials patented by Eltron, the membrane technology is significant to FutureGen because hydrogen derived from the process can be used to increase the efficiency of fuel cells and to fuel future hydrogen turbines, while, at the same time, separating carbon dioxide—a greenhouse gas—from the plant’s gas stream. DOE’s cost share of the project is just over $12 million. The project will be managed for DOE by the National Energy Technology Laboratory.

Building on membrane work first funded by DOE in early 2000, Eltron will conduct its research in three phases over 5 years. Initially, Eltron will strengthen its membrane to improve hydrogen flux and carbon dioxide sequestration potential. In phase 2, Eltron will scale up its membrane and impurity management system. In phase 3, the company will use a prototype system to separate an estimated 200 pounds of hydrogen per day, not unlike a commercial-size separation unit. All phases are expected to lead toward the design of a pre-commercial-size unit capable of separating an estimated 4 tons of hydrogen per day.

Eltron will be joined by an industrial partnership that includes Praxair, Tonawanda, N.Y.; CoorsTek, Golden, Colo.; Emery Energy Company, North Salt Lake, Utah; and Noram Engineering & Construct, Vancouver, Canada. Praxair will provide economic analyses and coal gas feed impurity management, CoorsTek will explore the cost-effective commercial-scale fabrication of membrane composites, Emery Energy will host field testing of membrane modules, and Noram will address engineering design and construction issues related to commercialization.

DOE initially expects to build a 275-megawatt prototype plant to serve as a large-scale engineering laboratory where clean power processes, carbon capture, and coal-to-hydrogen technologies can be tested. Advanced membranes, such as those under development by Eltron, are essential to reduce the cost of hydrogen production. As hydrogen becomes more affordable, it will increasingly find its place in the transportation sector, including hydrogen-driven cars; central power stations; and distributed power units.

The ultimate goal would be a decrease in the nation’s reliance on imported fuels and an energy-producing infrastructure emitting no greenhouse gases or other pollutants.
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Postby DomusAlbion » Wed 11 May 2005, 09:38:57

This is good news but what is the time frame for the envisioned prototype plant?
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Postby Egon_1 » Wed 11 May 2005, 12:24:04

$this->bbcode_second_pass_quote('', 'D')OE initially expects to build a 275-megawatt prototype plant to serve as a large-scale engineering laboratory where clean power processes, carbon capture, and coal-to-hydrogen technologies can be tested. Advanced membranes, such as those under development by Eltron, are essential to reduce the cost of hydrogen production. As hydrogen becomes more affordable, it will increasingly find its place in the transportation sector, including hydrogen-driven cars; central power stations; and distributed power units.


The cost of hydrogen itself is not the issue with using it for the described uses, and making it cheaper will not make it's use more prevalent.
The issue is the cost and durability of the hydrogen-to-power conversion technology.
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Postby ArimoDave » Wed 11 May 2005, 12:47:21

Let's see:

$this->bbcode_second_pass_quote('', 'D')OE initially expects to build a 275-megawatt prototype plant to serve as a large-scale engineering laboratory where clean power processes, carbon capture, and coal-to-hydrogen technologies can be tested. Advanced membranes, such as those under development by Eltron, are essential to reduce the cost of hydrogen production.

And
$this->bbcode_second_pass_quote('', 'I')n phase 3, the company will use a prototype system to separate an estimated 200 pounds of hydrogen per day, not unlike a commercial-size separation unit.


This seems to mean that the prototype plant will consume 275-megawatts, and produce 200 lbs of H2.

Anybody know off the top of their heads how many megawatts one can get out of 200 lbs of H2 (assume the mass is 90.7 kg) using a conventional fuel cell these days?

If the number is about 275-megawatts then they are not showing the input energy.

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Postby jockc » Wed 11 May 2005, 13:26:17

I'll answer for everyone. Please choose a response below:

1. This will never scale.
2. There isn't time to build enough of them
3. This only adds to the problem
4. Hydrogen is a joke
5. Hydrogen is an energy carrier!!!
6. It is morally wrong to use so much energy
7. it has a negative EROI
8. it costs way too much to build maintain and decommission
9. the economy is doomed anyway
10. ...?
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Postby ArimoDave » Wed 11 May 2005, 13:32:35

$this->bbcode_second_pass_quote('jockc', 'I')'ll answer for everyone. Please choose a response below:

1. This will never scale.
2. There isn't time to build enough of them
3. This only adds to the problem
4. Hydrogen is a joke
5. Hydrogen is an energy carrier!!!
6. It is morally wrong to use so much energy
7. it has a negative EROI
8. it costs way too much to build maintain and decommission
9. the economy is doomed anyway
10. ...?


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Postby parainwater » Wed 11 May 2005, 14:04:54

275 megawatts is equal to about 261,000 BTU per second.
I am not sure I understand their hydrogen production process
but normal electrolytic production of hydrogen runs about
70% efficiency. This would give 182,000 BTU per second of
hydrogen thermal energy equivalent. At 60,000 BTU per lbm
of thermal energy content for hydrogen this equates to about
3 pounds per second of hydrogen being generated for a 275
megawatt input. 3 lbm per second is equal to 259,000 lbm per
day. A gallon of gasoline has a thermal energy content of about
124,000 BTU per gallon. So 259,000x60,000/124,000 equals
125,000 gallons of gasoline equivalent per day. Considering
a typical coal fired power plant thermal efficency of 40%.
One must release 652,000 BTU per second of coal combustion
energy to produce 275 megawatts. Wyoming coal has a heating
value of around 12,000 BTU per lbm. So a 275 megawatt powerplant
must combust 54 lbm per second of coal = 2.33 kilotons per day. So in a nutshell one is using
652,000 BTU per second of coal energy to produce 259,000 BTU of
hydrogen energy. Or 2.33 kilotons of coal per day to produce 130 tons of hydrogen per day. This is first order calculation and can be further
refined for somewhat greater accuracy.
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Postby MicroHydro » Wed 11 May 2005, 14:11:35

And the CO2 will go where?
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Postby 0mar » Wed 11 May 2005, 17:36:55

if something has a fossil fuel input, it is by definition not sustainable. Using coal exacerbates global warming more-so than any other fossil fuel. Hydrogen has been shown to be one of the worst transportation alternatives because any means of self-sufficency is impossible without building solar panels the size of Alaska or covering every viable part of the world with windmills. Hydrogen needs fossil fuels to be competetive. Other alternatives do not, however, even those alternatives lack the versatility and scalability of oil.
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Postby BiGG » Wed 11 May 2005, 18:13:24

$this->bbcode_second_pass_quote('jockc', 'I')'ll answer for everyone. Please choose a response below:

1. This will never scale.
2. There isn't time to build enough of them
3. This only adds to the problem
4. Hydrogen is a joke
5. Hydrogen is an energy carrier!!!
6. It is morally wrong to use so much energy
7. it has a negative EROI
8. it costs way too much to build maintain and decommission
9. the economy is doomed anyway
10. ...?




10. Duh, it did all work ……… oh well ………… I guess we can at least still use our “The End of the World is Near!” & DOOM! DOOM! DOOM! signboards for card tables!
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