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THE Thermal Depolymerization Thread (merged)

Discussions of conventional and alternative energy production technologies.

Re: thermal depolymerization a end to peak oil?

Postby kublikhan » Tue 06 Jan 2009, 01:11:34

$this->bbcode_second_pass_quote('TomSaidak', 'A')nd yet another question.... Does anyone know if it is easier to get algae to produce lipid type fats and where I could research it?
You should probably check out the energy technology forum over here: Energy Technology

Most energy technology related threads wind up there. In fact this thread is probably better suited to that forum than Current Events. There are a couple of algae threads there. I think this one was most extensive:
Algae Oil Not Viable Until Oil Hits $800

You should also check at the website: The Oil Drum if you have not already. They post a number of peak oil/energy related articles on that sight and often delve down deep into the numbers. The have a number of articles on Algae:
Algae Biodiesel
Such as this one: The Man Who Wrote The Book On Algae Biodiesel

$this->bbcode_second_pass_quote('TomSaidak', 'A')nyway, thanks for the info. I will be busy crunching it. Is there anyway to post a spread sheet to this forum?
You can upload your spreadsheet to a website that allows free file hosting, such as FileFactory or MediaFire. Then after the upload is complete, post a link to that file in this forum, the website will give you the direct file link.
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Re: thermal depolymerization a end to peak oil?

Postby TomSaidak » Thu 08 Jan 2009, 14:37:53

Okay, here is the URL for my spreadsheet. Thanks for the suggestion Kublikhan. :)
My TDP spreadsheet
{Note Spreadsheet Revised 1/8/2009}
I apologize ahead of time if you don’t like the way I work my spreadsheets. Feel free to email me your version. If I like it, I will adopt and update accordingly. This file should work with anything that can except a 1997 to 2003 Excel Spreadsheet. If for some reason you cannot access the spreadsheet, let me know and I will try to email you directly.
I identified numerous feedstocks that would yield 32% of our current consumption. IF we mandated changes to power trains for transportation to more efficient drive trains, we could lower our consumption by 40%, which means the identified feedstocks would yield 54% of US consumption.
About comments. At this point the 10:1 ratio is meaningless for oil production. The figures are “hard figures” in that they represent documented amounts of matter and documented amounts of energy available. I really don’t care how the mass got there as long as it exists. If you spot a math error – let me know! This is not to say the 10:1 ratio is unimportant, but that it is not important HERE…. OTOH, debate about availability of a given feedstock IS, i.e. how much cow manure can we really use for oil.
About methods for determining energy….. In some cases I used BTU/mass. In those cases I multiplied by an additional 5/6 as I recall TDP uses 1 bbl out of every 6 to energize their process. In at least one case, I took the article at face value (Pig Manure), and then modified because of water content problems. So I may be off for these figures as I am assuming either TDP or CDP can wrestle out the BTU. If you have articles that would inform me on that subject do please send them my way!
For most of the feedstock, the oil produced was not significant. They did however address other environmental concerns. I included them for that reason alone, such as medical waste and sewage.
My intention is to arm rassle these figures first. I want to define what the deficit is so I know how big a hole to fill. I have already started that process by looking at Kenaf trees, which yield anywhere from .45 bbl per acre to 15+ bbl/acre, based on internet articles and calling people. I have given up on the internet and am calling people to verify numbers, as obviously at .45 bbl/acre, TDP is meaningless, while at 15 bbl/acre, TDP might well be a solution. More on that when a) I get some information I feel confident in, and b) I have time to play with my spreadsheets. I am starting a long term substitute teacher gig on 1/12, and this website has been sporadically hard or impossible to get to.
And remember – arm rasslers MUST bring beer! And if you bring any of that pale pilsner/light beer crud, I will pelt you with the individual cans or bottles. I prefer HEFTY ales. Same goes for lagers. I drink ALES – none of that sissy lager stuff!
Last edited by TomSaidak on Fri 09 Jan 2009, 02:19:37, edited 2 times in total.
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Re: thermal depolymerization a end to peak oil?

Postby TomSaidak » Thu 08 Jan 2009, 18:24:37

Pstarr wrote:

$this->bbcode_second_pass_quote('', 'T')hen you have no comprehension of net-energy analysis, eroie, or human/industrial ecology.


Okay, so lets run the numbers based on 10:1
163 Bushels of corn to the acre
222040 Kcal (food calories) per 10 bushels of corn.
93,000,000 acres planted in corn.
0.00396566683 btu per THERMAL calorie.
5800000 total btu in bbl
163/10 = 16.3 (multiplier for total Kcal per acre.)
222040*1000*16.3 = 3,619,252,000 total thermal calories per acre.
=93,000,000*3,619,252,000 = 3.3659*10^17 total thermal calories in 93,000,000 acres of corn.
3.3659*10^17/0.00396566683 = 1.33481*10^15 btu in all that corn.
1.33481*10^15/5800000 = 23013884 bbl of energy in corn.
Oil energy required as per Pstarr..
10*23013884 = 230138840.
230138840/(365*2100000)*100 = 30% of total US Oil Consumption.
30% Pstarr's Corn Energy Required Figure.
40% Passenger Car and Light Truck share of US Oil Consumption
26% Heavy Truck share of US Oil Consumption
7% US Air travel/transport share of US oil consumption.
20% Industrial share of Oil.
120%. Total Oil called for expressed as percentage of US oil consumption at 21,000,000 bbl per day.
So, either we ran out of oil in August, AND no trains or ships moved or bunkered in the US during 2008, or that 10:1 ratio doesn't apply here. Not to mention we didn't have enough oil for rice, wheat, sorghum, trees, cotton, grapes, barley ( I HATE not having beer....), hops (did I mention I HATE not having beer??), fish, beef, pork (no loss, I don't eat pork...), lamb, chicken, turkey, goat cheese, dairy products, plastic, paper, new cars (US Built, we can argue if that is good or bad elsewhere...), wine...........
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Re: thermal depolymerization a end to peak oil?

Postby kublikhan » Thu 08 Jan 2009, 20:15:10

$this->bbcode_second_pass_quote('TomSaidak', 'O')kay, here is the URL for my spreadsheet.
A few suggestions. When posting, use the link button(looks like a small globe with a change link behind it" to post links. Cleanup the spreadsheet a bit. Put what units you are using. Clearly label sources, etc.

About the numbers, I think you need to differentiate between waste material, and garbage that is discarded. Just because a potential feed stock is waste material, does not mean that our current system discards the material. For example, the "black liquor" waste stream generated by paper mills is waste and a potential feedstock. But our current system does not just discard the waste. They burn it in a recovery boiler to generate the energy they need. So if you are going to be taking away that energy from them, you have to replace it with another source of energy.

$this->bbcode_second_pass_quote('', 'T')he forest products industry generates 51% of its energy needs from biomass and black liquor.
Pulp And Papermill

$this->bbcode_second_pass_quote('', 'A')nother US pulp mill contact said black liquor, a byproduct of cooking wood chips, is burned in a recovery boiler and the heat value creates steam to power the pulp mill.
The contact added that the key problems with considering black liquor as a biodiesel source is in the reliability of the gasification process and the need to replace the energy source created from the black liquor. About two-thirds of the energy for running a pulp mill comes from the black liquor recovery.
Black Liquor

So I would not list the paper mill source since that energy is already allocated by our current system.
BTW, what conversion factor are you using when converting tons of mass into barrels of oil? And can you link to the source for that?

For the wastes that come from agriculture sources(manure, corn stover, etc), this should be used to maintain soil fertility. We should not be polluting water streams with it, or turning it into oil.

$this->bbcode_second_pass_quote('', 'M')anure is the oldest and most effective fertilizer known to man. As long as man has used domesticated animals and worked the soil, manure, which is sometimes referred to as "dung" has been used to feed the soil and plants. Manure can return 70 percent of the nitrogen, 75 percent of the phosphorus and 80 percent of the potash that was taken from the soil to feed the animals. This is not a bad return if you consider a dairy cow produces 27,000 pounds of manure per year.

For thousands of years this was the perfect system between man, animal and nature. Mother Nature, herself, invented this system. All we have to do is travel through the countryside and look at the forest to see this system in action. The plant life flourishes, taking nutrients and trace minerals from the soil. As the plant completes its life cycle, material is returned to the forest floor where it is mixed with animal waste, decomposes, is consumed by earthworms, and used to feed the next cycle of plant life.

The value of manure was still understood when man moved to the city. It was gathered, piled outside city gates where all could share in its value. Without manure to place in the field, the nutrients and trace minerals in the soil would soon be depleted and the land would no longer support a commercial crop. Part of what supported the westward movement in this country was the practice of early farmers using up the land and moving West to more fertile ground. It is sad that even today most farmers do not understand the proper use of manure and simply dump it on uncultivated land for disposal. Only about 1/4 to 1/3 of the true value of manure as a resource is realized in this country.
Manure
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Re: thermal depolymerization a end to peak oil?

Postby kublikhan » Thu 08 Jan 2009, 20:25:31

$this->bbcode_second_pass_quote('TomSaidak', 'O')kay, so lets run the numbers based on 10:1
That number is in energy equivalents. The energy is not just from oil. For example, most of the energy used to manufacture fertilizer comes from natural gas. The energy used for irrigation could come from diesel, natural gas, propane, electricity, etc. Also, that number includes transportation energy, which would already be included in oil use categories that you excluded from your example(such as trucking).
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Re: thermal depolymerization a end to peak oil?

Postby kublikhan » Thu 08 Jan 2009, 20:56:10

$this->bbcode_second_pass_quote('TomSaidak', 'T')his website has been sporadically hard or impossible to get to.
Try logging on at a different time of day. During high traffic times, this website slows down to a crawl or becomes impossible to access. But at low traffic times it is relatively snappy.
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Re: thermal depolymerization a end to peak oil?

Postby kublikhan » Thu 08 Jan 2009, 21:51:33

$this->bbcode_second_pass_quote('', 'C')WT still exists as a company today. Like cellulosic ethanol, TDP is a technology that actually works. But the technology was hyped beyond reason. People did not apply enough skepticism before embracing the promise of the technology. It was really going to be "the next big thing."

But costs and complications were grossly underestimated. They fell victim to The Law of Receding Horizons. They learned that the public doesn't like smelly plants in their community. Discover ran an updated article in 2006 in which Appel admitted "We have made mistakes. We were too aggressive in our earlier projections." The hype just ultimately did not match the reality. And while TDP may make some small contribution to our energy needs, it isn't going to make any measurable dent in our fossil fuel usage.

I remember when Discover published their first article about this. Many readers couldn't believe it, and wrote angry letters accusing Discover of falling for a perpetual motion scam.

I knew it wasn't a scam, but those objections pointed to what I saw as the real reason this technology was never going to replace imported oil. The feedstock, even if it was free monetarily, would not be free energy-wise. There's not enough turkey waste out there to replace oil, and it would be really silly to farm turkeys just to feed the thermal conversion plant. Assuming we could farm enough of them, which we can't.

I think this technology may prove to be a useful way of getting rid of waste - sewage, old tires, mad cow infected carcasses, etc. - but as a replacement for oil, it was never going to fly.

Basically, it's a form of recycling. Recycling is good, but it doesn't actually produce any new energy.
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Re: thermal depolymerization a end to peak oil?

Postby TomSaidak » Fri 09 Jan 2009, 00:09:02

Kublikhan Quoted:
$this->bbcode_second_pass_quote('', 'A')nother US pulp mill contact said black liquor, a byproduct of cooking wood chips, is burned in a recovery boiler and the heat value creates steam to power the pulp mill.
The contact added that the key problems with considering black liquor as a biodiesel source is in the reliability of the gasification process and the need to replace the energy source created from the black liquor. About two-thirds of the energy for running a pulp mill comes from the black liquor recovery.


An interesting point, that needs more research. [s]I will leave the number in for now, but will do a bit more research. Expect that it will go down. I will be looking for oil replacements and environmental impacts (where do all the nasty chemicals go). Also, MIT Pulp To Power[/s] I reduced the number by 75%, you can see the revised spreadsheet here:
My TDP Spreadsheet


MSW. I knew you were going to comment on that. I have changed that number. MSW now represents 2%.

First off, sow manure is unuseable for anything else, and is being blamed for creating a dead zone the size of New Jersey in the Gulf of Mexico. One of those factoids I have picked up.

Cow manure. Some of it SHOULD be put back into the soil. Not all of it - the soil can't utilize it. That is in numerous articles. The phopshates end up in the water. I know that is a problem personally - used to work a Renne Faire next to a reservoir, and no end of dicussion of problems caused by manure. Or vomiting drunks. Don't ask unless you really, really want me to explain.... This includes NOX emissions and methane emissions. Both of which are nasty air pollutants.
Much of the manure use can be replaced by NG. My Prius won't burn NG, but it will burn oil. So I suggest as a strategy that to the point we can find alternates to manure as fertilizer, use the maure for oil. The arm rassling from here should look like a series of numbers with citations. We both agree manure should be used as a fertilizer. The question becomes one of how much. That number should be based on a) how much can the soil accept (no point in putting 2lbs of manure in if the soil can only use 1lb) b) How much manure as fertilizer can be supplanted by non oil substances. We are talking Peak Oil issues, not peak NG issues. Though that will come up at some point..... ;)

So, get some manure numbers and you OWE ME BEER YOU RAT!!

Let's see....
Tons to bbl.... Convert tons to pounds by multiplying by 2000, divide by 7.7 lbs (weight of one gallon of oil), and divide by 42 gallons to get bbl. Silly Kublikhan - that's why I put up the spreadsheet - so you could SEE the formulaes!! [smilie=icon_cheers.gif]

Kublikhan wrote:
$this->bbcode_second_pass_quote('', 'T')hat number is in energy equivalents.

Yes, we have had that discussion. Pstarr likes to criticize, but has yet to EVER produce numbers when numbers are used. I started my posts with a number. You supplied counter arguements that included numbers. I have modified my numbers. This is in effect a science argument that will lead to an economic argument at some point. By the way, I use the term "argument" in it's mathematical/science context. You are being very polite and helpful. :)

Which reminds me, that 400 gallons of oil equivalent, after subtracting non oil energy sources, turns into about 1.6 billion bbl per year, which still strikes me as high. I can discount 45 percent or so as non oil sources of energy, but the various breakdowns leave a lot to be desired in teasing out electrical vs non electrical sources. It also leads me to wonder how much of that energy that IS oil based can be changed to non oil based sources.

And about agricultural sources in general. Places like Georgia University, which are Ag colleges keep talking about using cornstover and cotton stalks as biomass. So a number of peeps in the Ag business who also use fertilization costs in their number crunching are suggesting that such stocks be used for energy, not fertilizer. One source of efficiency is cost, if they can get more selling cornstover then it costs to fertilize, then it may be better to go that route. Frankly, there is some wriggle room for discussion there.
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Re: thermal depolymerization a end to peak oil?

Postby kublikhan » Fri 09 Jan 2009, 18:23:02

$this->bbcode_second_pass_quote('TomSaidak', 'C')ow manure. Some of it SHOULD be put back into the soil. Not all of it - the soil can't utilize it. That is in numerous articles. The phopshates end up in the water. I know that is a problem personally - used to work a Renne Faire next to a reservoir, and no end of dicussion of problems caused by manure. Or vomiting drunks. Don't ask unless you really, really want me to explain.... This includes NOX emissions and methane emissions. Both of which are nasty air pollutants.
Water runoff and odor problems can be addressed by using alternative farming methods, such as subsurface injection. And it's not a matter of more manure is generated than can be utilized. It's also things like livestock feedlots are not always mixed with croplands. Thus the manure would have to be hauled from the feedlots to the croplands. Application of organic fertilizer also is more labor intensive, and depending on natural gas prices could also be more expensive. But it is the route we need to take if we want to live sustainably.

$this->bbcode_second_pass_quote('', 'A')nother problem with extensive and abundant use of inorganic fertilizers is that their use does not improve soil fertility and structure over the long term. Further, as they are used more and more in place of alternative practices that do build the soil, we become increasingly dependent on their use -- an addiction.

SO, WHAT HAPPENS OVER TIME AS INORGANIC FERTILIZERS ARE USED IN PREFERENCE TO ORGANIC SOURCES OF FERTILITY?
A dramatic example of this loss of organic material in agricultural soils is in the midwestern US, whose prairie soils have lost 1/3 - 1/2 of their organic material since they began being cultivated. This is a common pattern: conversion to cropland is almost universally associated with a rapid decrease in soil organic matter and soil nitrogen content. High inputs of nitrogen fertilizers can also result in soil acidification. Essentially, as growers add inorganic fertilizers without due attention organics, they step onto a one-way street. The combination of factors described above means that they need to add ever-increasing amounts of inorganic fertilizers to sustain their yields. It is similar to any addiction, where increasing amounts of the desired substance are required to achieve satisfaction. The amounts of inorganic fertilizers required increase because natural inputs of fertility and the nutrient retentiveness of the system diminish.
Consequences For Organic Matter In Soil

$this->bbcode_second_pass_quote('', 'W')inter wheat-maize rotations are dominant cropping systems on the North China Plain, where recently the use of organic manure with grain crops has almost disappeared. This could reduce soil fertility and crop productivity in the long run. A 20-year field experiment was conducted to 1) assess the effect of inorganic and organic nutrient sources on yield and yield trends of both winter wheat and maize, 2) monitor the changes in soil organic matter content under continuous wheat-maize cropping with different soil fertility management schemes, and 3) identify reasons for yield trends observed in Xuzhou City, Jiangsu Province, over a 20-year period. There were eight treatments applied to both wheat and maize seasons: a control treatment (C); three inorganic fertilizers, that is, nitrogen (N), nitrogen and phosphorus (NP), and nitrogen, phosphorus and potassium (NPK); and addition of farmyard manure (FYM) to these four treatments, that is, M, MN, MNP, and MNPK. At the end of the experiment the MN, MNP, and MNPK treatments had the highest yields, about 7 t wheat ha−1 and 7.5 t maize ha−1, with each about 1 t ha−1 more than the NPK treatments. Over 20 years with FYM soil organic matter increased by 80% compared to only 10% with NPK, which explained yield increases.
Long Term Effect Of Manure And Inorganic Fertilizers

$this->bbcode_second_pass_quote('', 'T')he energy savings achieved by fertilizing with liquid manure instead of inorganic fertilizer ranged from 36 to 52% (calculated from Table IV data) over the three test sites. This is in good agreement with McKyes et al. (1986) who reported energy savings ranging from 38 to 47% when manure was substituted for inorganic fertilizer. Current recommendations are to incorporate manure, either by cultivation or subsurface injection to reduce both odor and ammonia losses which represent a loss in nitrogen available for crop production.

It should be emphasized that the savings reported for the manure based corn production are energy inputs and not necessarily economic. Many producers cite extra cost of manure based over fertilizer based corn production as a reason for not exploiting the manure resource. Most fertilizer application is done by the supplier/custom applicator and is only a phone call away. Manure based corn production requires extra labor and equipment and requires an additional level of management to ensure proper application uniformity, rate, and timing.

The analysis showed that the indirect energy requirement for the manufacture of inorganic fertilizer (starter fertilizer plus general broadcast fertilizer) represented the single largest energy input for no-till grain corn production and ranged from 40 to 50% of the total energy input. The analysis clearly shows the potential for substantial reduction in energy requirements for crop production by using livestock manure in place of inorganic fertilizer.
Comparison Of Energy Inputs
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Re: thermal depolymerization a end to peak oil?

Postby kublikhan » Fri 09 Jan 2009, 18:55:22

$this->bbcode_second_pass_quote('TomSaidak', ' ')Pstarr likes to criticize, but has yet to EVER produce numbers when numbers are used.

$this->bbcode_second_pass_quote('pstarr', 'T')he energy to make the TDP feedstock must be far more than the energy in the resulting fuel. It can be no other way.
This is basically the bottom line for this technology. Because of the laws of thermodynamics, you will get less energy out of the feedstock than the energy that was put into it. Now not all of that energy in the feedstocks came from fossil fuels. Some of the energy came from the sun. Tom, IMO if you want to show that this technology can replace a significant percentage of our fossil fuel usage, you would have to do the following. For the feedstocks you are promoting, show that the energy provided by the sun represents significantly more energy than the energy provided by fossil fuels. I don't think you are going to be able to do that. Perhaps crops grown pre Green Revolution style would fit that bill, but then those are grown at a much lower yield. Remember this quote if you want to get an idea of where the energy in your feedstocks comes from:

$this->bbcode_second_pass_quote('', 'B')etween 1950 and 1984, as the Green Revolution transformed agriculture around the globe, world grain production increased by 250%. That is a tremendous increase in the amount of food energy available for human consumption. This additional energy did not come from an increase in incipient sunlight, nor did it result from introducing agriculture to new vistas of land. The energy for the Green Revolution was provided by fossil fuels.
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Re: thermal depolymerization a end to peak oil?

Postby TomSaidak » Fri 09 Jan 2009, 20:04:55

Kublikhan wrote:
$this->bbcode_second_pass_quote('', 'T')his is basically the bottom line for this technology. Because of the laws of thermodynamics, you will get less energy out of the feedstock than the energy that was put into it. Now not all of that energy in the feedstocks came from fossil fuels. Some of the energy came from the sun.


Thank you. You finally put into words what I have beleived to be the central confusion of the 10:1 ratio regarding the Green Revolution and TDP is.....

I am going to ramble, but there IS method to my madness.......
In dealing with me, you need to know that a) In this arena, my "expertise" is in physics. Not biology. b) I work intuitively. The best example of this I can give is that Membrane Theory is EASY for me to understand, I can explain why the 11th dimension is about 2 to 3 feet long. I have tried my explanation on practicing cosmologists and physicists, and they LIKED it...

Thermodynamically speaking, NONE of the "10" calories represents ANY thermodynamic transfer of energy. This is why the word "nutrients" is used. Food is nutrients PLUS energy. Applied to humans and their diet, the word "nutrients" is called vitamins and minerals. ALL the energy found in food comes from the Sun. This is basic middle school science. Which I have taught. I have already given the numbers in my response to Pstarr, and demonstrated the fallacy of the 10:1 ratio looked at THERMODYNAMICALLY. The ratio is VALID looking ONLY at how we a) farm (get 163 bushels/acre as opposed to 16 or 4) and b) turn that corn into popcorn, corn, corn on the cob, corn flakes, corn bread, corn meal, etc.., and get it to the store in good enough shape to eat a year after it was grown. Pesticides make a good example. It takes energy to create it. It uses chemicals we would otherwise use as fuel (oil). It takes energy to apply it. It takes energy to get it OFF the foods we eat. Nowhere does it add to any energy stored in food. Refridgeration is another good example. We use it so that we can eat food LONG after we have harvested it, but NOWHERE does it add ANY energy to food. Milking MACHINES take energy, but NOWHERE does it add any energy to the milk we drink, butter milk, butter, cheese, sour cream or yogurt we eat. Churning machines are yet another example, as the act of churning does not add ONE calorie to butter. It simply TRANSFORMS cream into something some of us LIKE to eat. Corn silo's take energy to fill. Nowhere does it add to the energy content of food. Milling wheat takes energy, but adds NOTHING to the energy content of the food. Transportation adds NO eneregy to food from a biological viewpoint.

Kublikhan wrote:
$this->bbcode_second_pass_quote('', 'F')or the feedstocks you are promoting, show that the energy provided by the sun represents significantly more energy than the energy provided by fossil fuels.

I already have. I would suggest you start by attacking the numbers I used in my response to Pstarr. We can argue "concepts" until the cows come home. USE NUMBERS folks! This is SCIENCE, not editorials we are debating. I have demonstrated that using HALF of cow manure gets us 10.8% of US oil consumption, I have already demonstrated that solar power ADDS to the energy output. That scientists have already PROVED the thermal energy potential in WET cow manure is 2110 btu/POUND, and that has already PROVED that the 10:1 ratio doesn't control here. Please do NOT keep repeating the laws of thermodynamics when referring to Green Revolution numbers - you are mixing apples and oranges. If you disagree - cool. THEN USE NUMBERS AND PROVE IT FOLKS!!

{added}
About nutrients.... Think of each nutrient as a lego block. Pretend lego's represent atoms, not plastic which DID require oil.
You are presented with a bunch of lego blocks (atoms). You assemble the legos to make car/planes/trains/houses etc. As atoms, the legos did not add ONE btu or calorie of energy into the object you built. YOU supplied the energy. In this "thought experiment", you played the part of the sun.
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Re: thermal depolymerization a end to peak oil?

Postby MonteQuest » Fri 09 Jan 2009, 20:42:23

Man. I still see that a few fail to grasp that, in nature, there is no such thing as waste.

This waste is some other living thing's food.

Now, we want to deprive the fungi, bugs, and other detritivores their food so we can feed it to our machines.

Since we already apppropriate 40% of terrrestrial NPP, how much more do you think we can take from other living things and divert it to human use?

And to top it off, this is still trying to find a way to continue "happy-motoring."

We don't need more fuel for cars, or more cars for that matter, electric or otherwise.

This constant struggle for solutions for a continuation of an unsustainable existance is part of the problem, folks.

Give it up.
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Re: thermal depolymerization a end to peak oil?

Postby kublikhan » Fri 09 Jan 2009, 20:42:55

$this->bbcode_second_pass_quote('TomSaidak', 'A')LL the energy found in food comes from the Sun. Corn silo's take energy to fill. Nowhere does it add to the energy content of food. Milling wheat takes energy, but adds NOTHING to the energy content of the food. Please do NOT keep repeating the laws of thermodynamics. USE NUMBERS AND PROVE IT FOLKS!!

$this->bbcode_second_pass_quote('', 'T')he average U.S. system takes 10 calories oil invested to make 1 calorie of food energy. Growing food accounts for only one fifth of this. The other four-fifths is used to move, process, package, sell, and store food after it leaves the farm.
It is true that much of that 10:1 ratio could be cut if we took the crops from the fields and stuffed them directly into a TDP plant. So we could cut out silo filling, wheat milling, grain drying, etc. But according to the quote above, 1/5 of that energy is still used just to grow the crops. So that would be a 2:1 ratio. Plus you still need some energy on top of that to harvest the crop and stuff it into the TDP plant as well.

$this->bbcode_second_pass_quote('', 'i')n the United States, the amount of corn produced per hour of labor is today 350 times higher than the Cherokees could raise with their traditional agriculture. This enormous jump in farmer productivity would not have been possible without large injections of fossil energy and machine power. In fact, the flow of energy input in modern U. S. agriculture is 50 times higher than in traditional agriculture.
Population, Energy Use, And the Ecology Of Agriculture

Just because the energy stored in the corn kernel that gets fed into the TDP plant came from the sun does not mean that no non-sun energy was expended to grow the crop. You can't just say "the sun put 222040 Kcals in 10 bushels of corn. TDP uses 20% of that energy for itself. Therfore we transformed 222040 Kcals of sun provided corn energy into 177632 Kcals of oil" You have to look at the total amount of energy that was expended to grow that crop. Since TDP consumes 20% of the energy for itself, just to break even you would have to show that the sun provided at least 20% more energy than the energy that was expended growing the crop. How much energy did the farmer expend to grow those 10 bushels of corn?
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Re: thermal depolymerization a end to peak oil?

Postby TomSaidak » Fri 09 Jan 2009, 20:52:34

Kublikhan wrote:

Water runoff and odor problems can be addressed by using alternative farming methods

I wasn't referring to odor problems. I was referring to emissions. Manure gives of NOX and methane. To stop that, it has to be transformed. Soil can only transform it at a slow rate, during which the gas emissions continute. Chemically speaking, the odor comes from a third emission, which I believe is a hydrogen sulphide. Also not a good gas to just let go into the atmosphere. But humans can detect that at an incredibly low level, like 1 part in a million.

Hmm.. How to say this..... I am not concerned at this point with peak NG. I AM concerned about peak oil. IF I can stave that off or avoid it completely, mission accomplished for me. :). Keep in mind, there is going to be a deficit to fill. Solving that deficit may provide a solution too. In examining TDP/CDP as a solution, getting a number for current feedstocks is only the FIRST of several steps.

Also, the articles state specifically "more then the soil can handle". That is NOT an interpretation on my part, that is the conclusion of numerous scientists. Crop rotation plays a significant part in soil depletion as well. If corn farmers planted kenaf or soybean every other year, we wouldn't be having this discussion, as that would replace nitrogen. Grr... Trying to think of how it could be explored numerically. That it is causing problems with ground water is proof that it is "too much" as done. If you inject, that takes MORE energy. If you tranport it, that takes more energy as well. Gathering it takes energy, even from feedlots. Other questions that would help define the situation - are we experiencing fertility problems with Pasture lands? My experience even in pasture land there is a run off problem (signs of too much). Remember, water run off leads to ecological problems in water environments.
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Re: thermal depolymerization a end to peak oil?

Postby kublikhan » Fri 09 Jan 2009, 21:07:47

$this->bbcode_second_pass_quote('TomSaidak', 'A')lso, the articles state specifically "more then the soil can handle". That is NOT an interpretation on my part, that is the conclusion of numerous scientists.
For thousands of years humans more or less lived in balance with nature. Food goes in, manure comes out. Same with our domestic animals. We are not suddenly making more manure than the food we eat. The industrialization of agriculture is what has thrown this balance out of whack. Monte can probably explain it better than I. You might want to check out his post on why taking "waste" manure and turning it into oil is not such a good idea.
Last edited by kublikhan on Sat 10 Jan 2009, 04:54:28, edited 1 time in total.
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Re: thermal depolymerization a end to peak oil?

Postby MonteQuest » Fri 09 Jan 2009, 22:03:22

$this->bbcode_second_pass_quote('kublikhan', ' ') Monte can probably explain it better than I. You might want to check out his post on why taking "waste" manure and turning it into oil is not such a good idea.


Here is an article I wrote recently:

The Pure Folly of Large-scale Biofuels

We have seen many reports of late regarding the impact of feeding our food to our machines, from food shortages to escalating prices. Many propose that we move way from using corn and other foods to make biofuels. In a recent article I read, the author showed his ignorance of basic biological concepts by stating the following:

“Moving away from food crops, the biofuel of the future may come from the tall grass growing wild by the roadside, from grain stalks left behind by the harvest, and from garbage dumps and dinner table scraps. They don't compete with the food chain."

Implicit in this statement is that this organic waste stream is not used by anyone for food.

This type of residue may not compete with the human food chain, but they most certainly compete with the food chain of plants and other animals, upon which we are totally dependent. In nature, there is no such thing as waste. Wild grass, cornstalks, leaf litter, and other organic debris, are food sources for everything from fungi to bugs and other detritivores. Detritivores are scavengers which feed on dead plants and animals or their waste. They are essential for recycling of nutrients: without them dead plant material would not be returned to the soil for new growth. If we burn up this waste to feed our machines, what will replace the soil tilth?

“Removing "crop residues…would rob organic matter that is vital to the maintenance of soil fertility and tilth, leading to disastrous soil erosion levels. Not considered is the importance of plant residues as a primary source of energy for soil microbial activity. The most prudent course, clearly, is to continue to recycle most crop residues back into the soil, where they are vital in keeping organic matter levels high enough to make the soil more open to air and water, more resistant to soil erosion, and more productive."

The only true waste stream I can think of at the moment is nuclear. By diverting a supposed waste stream we are taking a resource from some other process. Equally, using land to grow anything is going to take away from its’ existing use, and there's very little arable land left on the planet that isn't being used for something, even if it's not us that's using it, but some other species that has as much right to live here as we have. We currently appropriate 40% of the earth’s terrestrial net primary production (NPP) to human use.

Sustainable biofuels have a place in our future energy mix, but not on the huge unsustainable scale that is often proposed to continue “happy motoring.”

For more on this subject, I invite you to review this article: Peak Soil: Why cellulosic ethanol, biofuels are unsustainable and a threat to America.
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Re: thermal depolymerization a end to peak oil?

Postby Tanada » Sat 10 Jan 2009, 08:06:09

$this->bbcode_second_pass_quote('MonteQuest', 'M')an. I still see that a few fail to grasp that, in nature, there is no such thing as waste.

This waste is some other living thing's food.

Now, we want to deprive the fungi, bugs, and other detritivores their food so we can feed it to our machines.

Since we already apppropriate 40% of terrrestrial NPP, how much more do you think we can take from other living things and divert it to human use?

And to top it off, this is still trying to find a way to continue "happy-motoring."

We don't need more fuel for cars, or more cars for that matter, electric or otherwise.

This constant struggle for solutions for a continuation of an unsustainable existance is part of the problem, folks.

Give it up.


The above statement is non-sensical. Plastic waste is nothings food. Asphalt waste is nothings food. Metalic waste is nothings food. Pressure or creosote treated lumber is nothings food and environmentally contaminating to boot. Gypsum board is nothings food in the landfill but can be rendered into a soil amendment in soils lacking sulfur.

Detrivores, if we were to recycle every bit of human caused waste, would have no shortage of food in leaf litter, grasslands, or croplands as far as that goes. Microbes are the dominant life forms on this planet, they always have been and they always will be, to claim we could do anything to change that or that we are starving the little beasties is huberistic in the extreme.

I think you should follow your own advice Monte and give it up, we do not all agree with you because facts do not back up your constant assertions. You might be right about some of the things you beleive are going to happen, but using statements contrary to reallity to try and prove you are right just makes you look desperate, wrong, and too proud to use truth and let people make their own minds up based on the facts, not the hype.

Hubris, pure unadulterated hubris. Sad really because I think you are an intelligent person with a real concern. Unfortunately the Emporer has no clothes.
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Re: thermal depolymerization a end to peak oil?

Postby dohboi » Sat 10 Jan 2009, 14:22:49

Umm, tanada, note that he said "in nature" right up there in the first line.

The point is that the more we make things that don't fit this natural cycle, the more we are dooming ourselves and everything else.

You might not like mq's rhetorical style, but the basic point is valid, IMVHO.
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