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PeakOil is You

THE Laws of Thermodynamics Thread (merged)

General discussions of the systemic, societal and civilisational effects of depletion.

Unread postby PenultimateManStanding » Wed 30 Mar 2005, 20:42:15

$this->bbcode_second_pass_quote('smiley', '
')That is a very fatalistic approach which leads to the idea that entropy leaves us no other option than to make a mess of things.
Precisely the point! The moment we stepped out of our natural roles on the planet, we began to have greater and greater entropic effect. In the big scheme of things (viewed from a rational scientific viewpoint) everything we do is causing disorder and disruption (on the macrocosmic level). This intellectual argument from the Evolutionists seeking to integrate their thought with Classical Thermodynamics seems to be quite credible to me.
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Unread postby WebHubbleTelescope » Wed 30 Mar 2005, 23:23:52

Pretty funny reading all the rantings on this subject. I suggest we all pick up a grad-level book on Statistical Mechanics to understand how this works at a fundamental level. Thermodynamics as taught in say MechEng amounts to a lot of hand-waving. To appreciate this, you really have to look at collections of particles and do the math. Stat Mech has an elegant beauty that rivals other branches of physics -- pretty obvious when you see how it bridges the gap between quantum and classical laws.

Reif wrote a classic book on the subject.
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Unread postby PenultimateManStanding » Wed 30 Mar 2005, 23:33:50

Hit and run! sneak attack! 'you guys crack me up, go muscle up with some real graduate level physics! - come back when you really know something' Well if 'paradigm' has to suffer from onslaughts of the uneducated rabble then I suggest 'entropy' has to get the same treatment! (jeez, thinks he's Einstein and a bag of chips, too!)
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Unread postby WebHubbleTelescope » Thu 31 Mar 2005, 00:35:52

Super Dave is performed by none other than Bob Einstein. Super Dave's brother is Albert Brooks.

Compared to Einstein. Pretty good snark company.
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Unread postby PenultimateManStanding » Thu 31 Mar 2005, 00:47:36

What is this, Web, some sort of display of entropy in action? Conversational Entropy for Idiots? And who the hell is Super Dave?
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Unread postby Keith_McClary » Thu 31 Mar 2005, 01:04:33

$this->bbcode_second_pass_quote('MonteQuest', '
')AND your house can spontaneously jump up, make a somersault and land on its foundations. However the odds of such an occurrence are infinitely small.

And the odds of my insurance company covering the damage are also infinitely small.
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Unread postby Mercani » Thu 31 Mar 2005, 02:25:52

$this->bbcode_second_pass_quote('Dolly', '
')
The Earth isn't an isolated system.



You, defenders of 2nd law, should understand the above sentence first before trying to argue "humans are doomed because entropy increases".
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Unread postby MonteQuest » Thu 31 Mar 2005, 02:43:19

$this->bbcode_second_pass_quote('Mercani', '')$this->bbcode_second_pass_quote('Dolly', '
')
The Earth isn't an isolated system.



You, defenders of 2nd law, should understand the above sentence first before trying to argue "humans are doomed because entropy increases".


Again, for the umpteenth time, no one is arguing that there is a thermodynamic equillibrium problem with space!

The problem is that we are dependent upon a phantom neg-entropy in the form of "fossil fuels" to hold entropy at bay right here on earth. We would never have achieved this level of complexity without it. We are not living off of received diffused solar, but stored concentrated solar.
Last edited by MonteQuest on Sat 02 Apr 2005, 21:46:27, edited 1 time in total.
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Unread postby WebHubbleTelescope » Thu 31 Mar 2005, 02:50:37

$this->bbcode_second_pass_quote('PenultimateManStanding', 'A')nd who the hell is Super Dave?


Super Dave is Bob Einstein. As in Einstein, the guy you were trying to compare me to.

Too bad his brother Albert Einstein only makes comedies every 10 years or so. They're all classics: Real Life, Lost in America, etc.
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Unread postby Antimatter » Thu 31 Mar 2005, 02:53:29

$this->bbcode_second_pass_quote('smiley', 'T')here is no entropic driving force for us spoiling our earth, no excuse, other than human sloppiness.


I agree. The increase in number of equivalent microstates from our activities is insignificant compared to the natural energy flux and has nothing to do with pollution, species loss, depleted fisheries etc. Arguing otherwise requires using the concept of "social entropy" or suchlike which is not related to thermodynamics. The "technology transforms energy and thus more tech will use energy faster due to second law" feels a bit dodgy to me too: a high-tech hybrid will use less energy than a Hummer. On the other hand, the humble bicycle will of course use much less energy than either. While the general trend of technological advancement has seen increasing energy useage, it doesn't have to be that way.
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Unread postby smiley » Thu 31 Mar 2005, 06:30:16

$this->bbcode_second_pass_quote('PenultimateManStanding', 'P')recisely the point! The moment we stepped out of our natural roles on the planet, we began to have greater and greater entropic effect. In the big scheme of things (viewed from a rational scientific viewpoint) everything we do is causing disorder and disruption (on the macrocosmic level). This intellectual argument from the Evolutionists seeking to integrate their thought with Classical Thermodynamics seems to be quite credible to me.


Yes it seems very logical. That's the problem.

If I use the example of Kochevic. He argues that by digging up iron ores and scattering them around the earth we create a mess. Since mess equals high entropy in his book he is convinced that the entropy increases by this action.

If you calculate the entropy you will see that the most important contribution to the entropy is not the displacement of the iron, but the state it is in. Iron ores have a higher entropy than simple iron oxides (rust) so by converting iron ores into rust you decrease the entropy. It doesn't make a difference whether you scatter this rust over the earth's surface or dump it back in the mine it came from.

Of course according to the 2nd law the entropy must increase somewhere else but that is besides the point. The point is that what we perceive as disorder does not necessarily represent a higher entropy.

To give another example. Imagine a stack of papers laying on your desk. You can arrange those papers in a number of ways. Some ways you'll perceive as disordered. If you arrange them on date or author you will perceive that as order. Then it is very tempting to say that those 'ordered' arrangements have a lower entropy than the 'disordered' ones and that is exactly what the evolutionists are doing.

But this is of course not the case. Since those papers are merely sheets of paper with an almost identical amount of ink on it, it doesn't make any difference in which way you stack them. There is no driving force to rearrange the stack into a less ordered way. If you leave them there and return after a week, a month or a hundred years, those papers will be in exactly the same order.

The evolutionists will argue that if humans come along, they will most certainly rearrange the papers in a disordered way. That I cannot deny, but since the entropy of the stack does not change entropy is not to blame.

Humans indeed seem a driving force for disorder, but we do so on our own accord, we're not forced by some physical law. That means that there is no excuse why we shouldn't change our ways.

$this->bbcode_second_pass_quote('montequest', 'T')he problem is that we are dependent upon a phantom neg-entropy in the form of "fossil fuels" to hold entropy at bay right here on earth. We would never have achieved this level of complexity without it. We are not living off of received diffused solar, but stored concentrated solar.


Even if you exclude space (which would be thermodynamically very incorrect), the system is much to complicated to describe in terms of entropy.

And why should you? The problem is very simple and can be well described by the first law. Our society depends on work. The first law tells you that in order to get work done you need energy. The first law also tells you that you cannot get this energy for free.

So in order to get our work done, we convert potential energy which is stored in our fossil fuels into work. Since we only have a limited amount of fossil fuels we will run out unless we find another source of energy. If that source is not unlimited on a human timescale we will eventually run out of that as well.

Why make things more complicated than they really are?
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Unread postby Mercani » Thu 31 Mar 2005, 08:52:49

$this->bbcode_second_pass_quote('smiley', '
')
Why make things more complicated than they really are?



Conservation of energy, or "first law", is not good enough to say that we are doomed. Because we are receiving enormous amount of energy from the Sun which is more than enough for our present civilization. We may not have the necessary means to convert most of this energy to useful work, but this has nothing to do with thermodynamics.

I think it feels good for some to use physical solid scientific laws to prove that we are doomed.

Nobody can prove that a man will die in the future, but it is a certain fact. Same with humanity.

You don't need to (and cannot) prove every fact.
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Unread postby Doly » Thu 31 Mar 2005, 09:34:09

$this->bbcode_second_pass_quote('MonteQuest', '
')Because every activity we do is governed by the 2nd law is why. How many people understand there are no free lunches? If everone understood the limits on energy constrained by 2nd Law, do you think they would still be buying the "hydrogen" economy?


The problem with hydrogen economy is simply that hydrogen in free form doesn't exist on the surface of the Earth, and many people don't know that. When you know that hydrogen needs energy to produce, you don't need to consider energy losses to see there's a problem. And if you do consider energy losses, they are a consequence of the 1st law, not the 2nd.

$this->bbcode_second_pass_quote('MonteQuest', '
')The problem is that we are dependent upon a phantom neg-entropy in the form of "fossil fuels" to hold entropy at bay right here on earth. We would never have achieved this level of complexity without it. We are not living off of received diffused solar, but stored concentrated solar.


The negative entropy found in oil is less than the negative entropy found in plants. We could have achieved this level of technology on plant-based products exclusively (many vegetable oils can be used as biodiesel on current motors). But we may not have achieved this level of population, because food-producing crops would be competing with fuel-producing crops.
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Unread postby CalgaryEng » Fri 01 Apr 2005, 02:11:00

This is a variation of a post I made six months ago.

I took a graduate course in thermodynamics in 1982 within a faculty of mechanical engineering. The text was "Classical Thermodynamics" by A.B. Pippard, Cavendish Professor of Physics at Cambridge.

The second law of thermodynamics (Clausius approach):

$this->bbcode_second_pass_quote('', 'I')t is impossible to devise an engine which, working in a cycle, shall produce no effect other than the transfer of heat from a colder to a hotter body.


There is nothing about statistics here. There is nothing about atoms. This is not the basis of a religious philosophy. It tells us nothing about the pros and cons of a hydrogen economy. There is not even the mention of entropy here. Thermodynamics has to do with temperature and heat.

You do not need to know about thermodynamics to know that when your car runs out of gas that it is not reasonable to wait for the products of combustion to magically reconstitute themselves into gasoline and pour themselves back into your tank.

Most people know that they have to plug their refrigerator into an electrical socket to get it to work. That is a direct consequence of the Clausisus statement. You cannot move heat from cold to hot (that is what refrigerators do) without doing some work.

That is what it is really all about. Put a refrigerator on the market that works without a power supply and we can throw away the second law as some old superstition.

Hydrogen is a means of storing energy just like oil. It is a lot less convenient than oil. However, both take energy to make. The biggest difference is that Mother Nature made a whole bunch of oil and stored it underground for us. We have to make hydrogen from scratch.

There is no shortage of energy. The radiation we get from the sun is simply enormous and of very high quality. The trick is to make it do something useful from a human point of view.

I believe that technology can provide sustainable solutions to all our energy problems. However, these solutions do not include anything that looks remotely like the monstrosity that has been created with the help cheap oil. The notion that the basis of an advanced civilization is to cover the earth's fertile land with asphalt, pollute its waters, and basically kill it in everyway possible to make room for unending growth is preposterous. It just will not work. You do not need laws of thermodynamics to tell you this or prove this. All you need is a little sense.
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The entropy of the universe always increases

Unread postby Infinity314159 » Mon 04 Apr 2005, 00:21:55

The statement that "evolution decreases entropy" is incorrect. The entropy of the universe (system+surroundings) always increases on the macroscopic scale. The thing with life is that the entropy of the living organism may decrease at times, but the entropy of the surroundings increases more than enough to compensate, and therefore the entropy of the universe (system+surroundings), is net positive over time. At macroscopic scales, the probability that this will not occur is so fantastically small as to be completely irrelevent to any discussion of what may plausibly occur. In fact, the thermodynamic definition of a "spontaneous process" is one in which delta S is positive (there is a net increase in entropy).
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Should You be Freaking About Oil Peaking?

Unread postby advancedatheist » Wed 01 Jun 2005, 23:09:15

The fallacious economic assumptions and ignorance of thermodynamics stand out right away -- Mark Plus:

http://www.manyworlds.com/popwins/print ... 1605116448

Should You be Freaking About Oil Peaking?
ManyWorlds by Max More
Editor reviewed on 05/16/2005, published on 05/22/2005

High gasoline and oil prices have renewed talk of “peak oil”, referring to the concept of Hubbert’s peak. In 1956, Shell geologist, M. King Hubbert, predicted that oil production in America would peak and begin to decline in the early 1970s. These days, we’re more interested in when we might reach a global “Hubbert’s peak.” The term is typically used by those making the most pessimistic estimates—people such as Colin Campbell and Jean Laherrere who, in a 1998 Scientific American article, predicted a global peak for right about now. Based on a comprehensive study in 2000, the United States Geological Survey concluded that we would not reach a peak for at least two decades. Where does the truth lie, and how confident can we be of an answer?

It’s commonly believed that oil is a non-renewable resource that must run out at some point in the future. Both parts of that belief can be challenged. Oil naturally renews—at an extremely slow rate—but technology might eventually replenish some of the supply at an economic cost. Even if this doesn’t happen, oil is highly unlikely to “run out.” As shortages intensify, prices will rise (so long as they are not controlled), and we will move away from this resource, despite the pain of doing so.

Even if oil is renewable (to some extent) and will not actually be exhausted, a peak in oil production followed by a decline is likely to rattle the global economy. How severely we will be rattled depends on how well we anticipate the date of peak oil, and what we do about it. Oil industry executives are far from the only ones who want to know the precise shape of oil production’s trajectory and when it will peak. Any such assessment will need to estimate remaining oil reserves, trends in consumption, and changes in extraction technology. None of these things is easy to do.

The first obstacle to accurate forecasts and estimates comes in the form of distorted perceptions. News headlines incessantly tell us of “record oil prices” as we float around the $50 mark. In reality, if you will forgive the metaphor, $50 oil can’t hold a candle to the inflation-adjusted $80 oil of the late 1970s and early 1980s. Although Americans gripe about the cost of gasoline, Europeans find the distress amusing, being used to paying far more. Despite the complaining, high gas prices may be of little consequence to the economy, the additional cost still making up a small fraction of the total cost of automobile ownership. Although today’s oil and gasoline costs are less dreadful than often supposed, continued growth in demand accompanied by a peaking of production would undoubtedly pose some major challenges. So how much do we have left?

To figure out the likely date of a peak, and the curve of the slope up and down, the first tricky thing we need to estimate is the size of remaining oil reserves. Sounds simple. The reality is complicated by several factors, the first of which is a lack of transparency. As The Economist pointed out in “The Incredible Shrinking Companies” (in the April 30, 2005 issue), the information needed to know whether oil reserves are running low simply isn’t being made available. One big problem is resource nationalism—most of the oil industry consists of national oil companies, which are not open with their reserve information.

We also have problems with private oil companies, though the blame lies less in their court than in that of the SEC. The agency’s rules were written in a different time. The restrictions on booking reserves are now arbitrary and excessive, forcing massive write-offs simply because the price of oil falls, not because the physical facts have changed. The oil industry can’t entirely shrug off responsibility, however. As The Economist notes, the industry could follow the example of the global mining industry, which already voluntarily discloses reserves.

Added to the transparency challenge, we have to beware of misunderstanding the concept of “reserves.” Oil pessimist Campbell has said: “Understanding depletion is simple. Think of an Irish pub. The glass starts full and ends empty. There are only so many more drinks to closing time. It's the same with oil. We have to find the bar before we can drink what's in it.” This is mistaken. Oil reserves are not fixed in any very meaningful sense. Reserves are an estimate of the amount of oil in reservoirs that can be extracted at an assumed cost, given the current level of technology. From a long-term historical perspective, you could say (as does Peter Odell of Rotterdam’s Erasmus University) that the world has been ‘running into oil’ rather than ‘out of it’.

Even as the world has used more and more oil over the past few decades, expert estimates of the recoverable resource base have consistently grown, driven by both economic forces and the effects of technological innovation. According to Odell, while the world has consumed less than 800 billion barrels of oil since 1971, during the same period we have added over 1,500 billion barrels to reserves. How much oil is ultimately recoverable depends to a great extent on how much we will spend to get it, and on how good is our extraction technology. In other words, reserves are dynamic, not static. Of course, it also depends on the quality of unexploited, or minimally exploited, frontiers. As The Economist article shows, no shortage of frontiers remain, although some of them are currently blocked by political factors.

On top of challenges in estimating the dynamically changing size of reserves, forecasts have to accommodate a changing oil recovery rate. A few decades ago, oil companies could extract about 20 percent of what they found. Today, with superior technology, the figure is around 35 percent. 25 years ago, the success rate for exploration wells was about one in six. Today, about two-thirds hit pay-dirt. While oil pessimists simply write off oil in locations already tapped, we should remember that two-thirds of the oil proven to exist in identified reservoirs remains available for future technologies to extract. New advances could move the global Hubbert’s peak quite a way further into the stratosphere.

Finally, we need to factor in various possible changes in energy consumption and efficiency. This also depends heavily on economic factors and on technological innovation. Back in 1973, looking ahead ten years and thirty years, few would have predicted what actually happened to oil consumption as economic growth continued: The United States used 35 quadrillion BTUs (quads) of oil in 1973. That number declined to 30 quads in 1980. In 2003, after two decades of economic growth, the number had reached only 39 quads. How much more efficient could we become in the face of genuinely high prices and accompanying government policies?

All these considerations, and others, make it look impossibly hard to accurately forecast a peak. However, we should consider that markets are usually correct over the long run, and the still fairly modest prices in the oil market suggest that a peak is not terribly near. If the smart money expected a great rise in oil prices a few years in the future, they would have bid up the price now. This hasn’t happened. Either the market is strongly and persistently irrational, or warnings of imminent Peak Oil are wrong.

If we’re not satisfied to rely on oil futures markets, some international institution could set up a decision market that allows people to make bids on forecasts of oil prices or reserves at various points in the future. Such a market could be valuable, especially if bids were also allowed on various proposed regulations or policies aimed at improving energy efficiency or encouraging alternative sources. Governments should be careful to avoid premature, poorly targeted, very expensive actions. Doing something can be every bit as bad as doing nothing. Decision markets which have been under-utilized to date, could be the perfect vehicle for harnessing globally distributed knowledge to improve our accuracy in forecasting oil prices, reserves, consumption, and possible peak.
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Unread postby 0mar » Thu 02 Jun 2005, 00:09:38

All the efficencies in the world make fucking squat if you need 20mbd of oil a day and can only get 18 mbd.
Joseph Stalin
"It is enough that the people know there was an election. The people who cast the votes decide nothing. The people who count the votes decide everything. "
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Re: Should You be Freaking About Oil Peaking?

Unread postby advancedatheist » Thu 02 Jun 2005, 19:29:39

$this->bbcode_second_pass_quote('', 'E')ven as the world has used more and more oil over the past few decades, expert estimates of the recoverable resource base have consistently grown, driven by both economic forces and the effects of technological innovation. According to Odell, while the world has consumed less than 800 billion barrels of oil since 1971, during the same period we have added over 1,500 billion barrels to reserves. How much oil is ultimately recoverable depends to a great extent on how much we will spend to get it, and on how good is our extraction technology. In other words, reserves are dynamic, not static. Of course, it also depends on the quality of unexploited, or minimally exploited, frontiers. As The Economist article shows, no shortage of frontiers remain, although some of them are currently blocked by political factors.


Where do these increasing new "reserves" reside? Oil companies have lost interest in the Caspian region, for example, because they found they had over-estimated the amount of recoverable oil there.

And you wouldn't know from reading this that thermodynamics exists.
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"The purpose of life is to disperse energy"

Unread postby killJOY » Thu 05 Jan 2006, 14:39:16

I was perusing this list of scientists discussing their favorite "dangerous ideas," depressed that not one of them mentions oil peak, when I came across this:

$this->bbcode_second_pass_quote('SCOTT SAMPSON', '
')The dangerous idea is this: the purpose of life is to disperse energy.

Many of us are at least somewhat familiar with the second law of thermodynamics, the unwavering propensity of energy to disperse and, in doing so, transition from high quality to low quality forms. More generally, as stated by ecologist Eric Schneider, "nature abhors a gradient," where a gradient is simply a difference over a distance — for example, in temperature or pressure. Open physical systems — including those of the atmosphere, hydrosphere, and geosphere — all embody this law, being driven by the dispersal of energy, particularly the flow of heat, continually attempting to achieve equilibrium.
[snip]
Virtually all organisms, including humans, are, in a real sense, sunlight transmogrified, temporary waypoints in the flow of energy. Ecological succession, viewed from a thermodynamic perspective, is a process that maximizes the capture and degradation of energy.
[snip]
Ecology has been summarized by the pithy statement, "energy flows, matter cycles. " Yet this maxim applies equally to complex systems in the non-living world; indeed it literally unites the biosphere with the physical realm. More and more, it appears that complex, cycling, swirling systems of matter have a natural tendency to emerge in the face of energy gradients. This recurrent phenomenon may even have been the driving force behind life's origins.
[snip]
The concept of life as energy flow, once fully digested, is profound. Just as Darwin fundamentally connected humans to the non-human world, a thermodynamic perspective connects life inextricably to the non-living world. This dangerous idea, once broadly distributed and understood, is likely to provoke reaction from many sectors, including religion and science. The wondrous diversity and complexity of life through time, far from being the product of intelligent design, is a natural phenomenon intimately linked to the physical realm of energy flow.


Read the whole thing.

So it would seem our tendency to chew our way through energy reserves is natural behaviour, the way things should be. And then we die.
Last edited by killJOY on Thu 05 Jan 2006, 15:50:55, edited 1 time in total.
Peak oil = comet Kohoutek.
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Re: "The purpose of life is to disperse energy"

Unread postby basil_hayden » Thu 05 Jan 2006, 14:52:55

"Use the Force, Luke." - Obi-Wan Kenobi

I'm not sure if life's purpose is to disperse energy or not, but certainly one purpose of life is to grow, and energy is needed to keep growing.

Can there still be life with no growth? Not sure yet. Can there still be growth with less energy? I believe so, maximizing efficiency.

Born to die, I guess.
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