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THE Laws of Thermodynamics Thread (merged)

General discussions of the systemic, societal and civilisational effects of depletion.

Postby Mercani » Tue 29 Mar 2005, 04:24:58

The universe is a closed and isolated system where 2nd law can definitely be applied.

The interesting fact is that, life is flourishing in this universe. Living beings as complex as humans exist. This complexity is clearly not a dis-ordered state. From a simpler point of view there are stars in the universe shining with millions of degrees of temperature and yet there are also vast emptiness in-between at close to absolute zero temperatures. There are local maximums of entropy and minimums of entropy scattered around although the total entropy must obey the 2nd law.

The 2nd law says nothing about "how" this local minimums and maximums are distributed. Why do they exist in their current state? These problems are not answered by thermodynamics.
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Postby MonteQuest » Tue 29 Mar 2005, 20:20:31

$this->bbcode_second_pass_quote('Mercani', 'T')he universe is a closed and isolated system where 2nd law can definitely be applied.

The interesting fact is that, life is flourishing in this universe. Living beings as complex as humans exist. This complexity is clearly not a dis-ordered state. From a simpler point of view there are stars in the universe shining with millions of degrees of temperature and yet there are also vast emptiness in-between at close to absolute zero temperatures. There are local maximums of entropy and minimums of entropy scattered around although the total entropy must obey the 2nd law.

The 2nd law says nothing about "how" this local minimums and maximums are distributed. Why do they exist in their current state? These problems are not answered by thermodynamics.


Ah, but herein lies the explanation. We are so used to thinking of biological evolution in terms of progress, but each higher species in the evolutionary chain transforms greater amounts of energy form a usable to and unusable state. As a species evolves, each succeeding species is more complex and thus better equipped as a transformer of energy. And here lies the answer—the higher the species in the chain, the greater the flow-thru ( as I explained in my earlier post) and the greater the disorder created in the overall environment.

2nd Law says that evolution dissipates the overall available energy for life. Our concept of evolution is the exact opposite. Evolution does not magically create greater overall value and order. Look around you at the ever increasing dissipated disorder in our environment. Evolution creates complex order yes, but only at the expense of creating an even greater disorder in the world. Ass backwards, you say? That is only because we are so locked into the existing world paradigm that all other ways of thinking seem unacceptable. 2nd Law is the basis for both life and evolution.

Living things cannot obtain thermodynamic equilibrium or they die, either by heatstroke or hyperthermia as the body tries to equalize with the surrounding environment. The constant flow-thru of neg-entropy keeps us at a non-equilibrium or steady state.

As to your point about the heat of stars and the cold of space, why is that so hard to grasp? Space is mostly a vacuum, with no matter or mass to absorb heat. Heat comes from the sun and warms the earth, and the vacuum of space in between is at near absolute zero. No mystery, no contradiction to 2nd law. Heat flows from a warmer body to a colder body. The vacuum of space is not a body.
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Postby BabyPeanut » Tue 29 Mar 2005, 21:51:56

$this->bbcode_second_pass_quote('MonteQuest', '')$this->bbcode_second_pass_quote('BabyPeanut', 'T')he point is that evolution decreases entropy.


How so? I just explained how it does not.

Not once did you use the word "evolution" in your explanation. You wrote about individual bodies, not the process of one object creating a "platform" that a more complex object can emerge from.

.
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Postby PenultimateManStanding » Tue 29 Mar 2005, 22:40:17

Lynn Margulis in her book Acquiring Genomes writes about the link between evolution and thermodynamics.

$this->bbcode_second_pass_quote('', 'L')ife is one of a class of systems that organize in response to a gradient. . . All of these systems produce unexpectedly complex features. Temperature gradients produce highly organized fluids, octagonal convection currents called Benard cells. [other examples include tornados and chemical 'clocks'.] A crucial point here is that not only is life consistent with the Second Law of Thermodynamics. . . but that complex systems reduce the gradients around them more effectively and quickly than would be the case were they not to exist.
This is a consequence of the Law of Least Action (i.e. water always finds the quickest way downhill. The argument basically states that life evovled as the most efficient way to dissipate the temperature gradient on Earth caused by the Sun. There it is: THE MEANING OF LIFE.
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Postby MonteQuest » Tue 29 Mar 2005, 22:46:10

$this->bbcode_second_pass_quote('BabyPeanut', '')$this->bbcode_second_pass_quote('MonteQuest', '')$this->bbcode_second_pass_quote('BabyPeanut', 'T')he point is that evolution decreases entropy.


How so? I just explained how it does not.

Not once did you use the word "evolution" in your explanation. You wrote about individual bodies, not the process of one object creating a "platform" that a more complex object can emerge from.

.


Sorry, I have it so ingrained in my head that I though it was obvious. And if you think it through, you end up with that realization. It all must balance.
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Postby PenultimateManStanding » Tue 29 Mar 2005, 22:51:24

Now this gradient reduction business would explain quite a lot of things. For instance, humor. Humor is an efficient way to reduce a psychological gradient, or tension, which is why we like it Or sex which reduces a biochemical gradient and why we like that, too. It's all so clear now, isn't it? In fact, the most effective way to reduce the psychological gradients within us is death which is why we ought to like that too. (Have at it DJ)
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Postby JohnDenver » Tue 29 Mar 2005, 22:57:34

$this->bbcode_second_pass_quote('PenultimateManStanding', 'T')he argument basically states that life evovled as the most efficient way to dissipate the temperature gradient on Earth caused by the Sun. There it is: THE MEANING OF LIFE.


Interesting... I've sometimes had the strange idea that entropy itself is the simplest form of life. It feeds on high-grade energy in order to perpetuate and spread.
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Postby PenultimateManStanding » Tue 29 Mar 2005, 23:24:35

But of course, death as the ultimate personal gradient reducer is very selfish. We are obligated to each do our part in the Big Scheme of Things which is to pitch in and reduce that goddamn thermal gratient. So go ahead and cop out DJ, but that just means that the rest of us will have to carry the load you selfish whiner.
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Postby 0mar » Tue 29 Mar 2005, 23:26:13

Protons actually do decay at something like 10^20 years or something. There's a huge underground facility in Japan that holds something like 2 million gallons of water looking for a decay of a proton.
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Postby smiley » Wed 30 Mar 2005, 05:48:20

The thermodynamic law is indeed statistical. The correct way to look at it is:

Every state has an equal chance of occurring. Since there are more 'disordered' states than 'ordered', a change is statistically more likely to result in a 'disordered' state than a 'ordered' one.

This means that the opposite can also happen. My house can spontaneously jump up, make a somersault and land on its foundations. However the odds of such an occurrence are infinitely small.

Entropy describes by the number of possible states or what we call complexions.

A high entropy thus means that the system can be arranged in many ways.

It is important to notice that entropy itself does not discriminate between ordered and disordered states. It is wrong to equal entropy with 'disorder'. An 'ordered' state can have exactly the same entropy as and 'disordered' state, although the latter has a larger chance of occurring.

However an important question is: what is 'disorder'? People who use thermodynamics, are hesitant to use the word disorder. The problem is is that disorder is a human qualification, a matter of perception. My girlfriend says that my room is disordered, I perceive it to be pretty ordered, thermodynamics might view it completely different.

When you start applying thermodynamics to complex things like evolution you run into two problems. One is that you cannot possible calculate the number of possible states. This is already terribly difficult for a system with more than six components, let alone a system which involves planets plants, animals etc. Therefore you cannot say that one configuration has a higher entropy than another. Secondly you cannot use your personal human definition of order to quantify the amount of disorder.

It is therefore pretty useless to try to use thermodynamics in an intuitive way to predict the fate of the human race.
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Postby Mercani » Wed 30 Mar 2005, 10:40:59

$this->bbcode_second_pass_quote('smiley', '
')
It is therefore pretty useless to try to use thermodynamics in an intuitive way to predict the fate of the human race.



I agree.
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Postby JohnDenver » Wed 30 Mar 2005, 10:46:48

$this->bbcode_second_pass_quote('smiley', 'I')t is important to notice that entropy itself does not discriminate between ordered and disordered states. It is wrong to equal entropy with 'disorder'.


I think it's closer to 'homogeneity". For example, you start with an aquarium partitioned into two sides -- blue fish on one side and yellow fish on the other. You remove the partition, and entropy begins to work at the boundary, where the blue and yellow begin to mix or blur into each other. If you squint your eyes, the mixing zone looks green. Wait a while and the whole tank looks green. Blue and yellow are totally and completely mixed. The result isn't "untidy" or "disorganized" like a messy room. In fact, it has a simple, perfect, almost-crystalline organization. (Like a crystal, all local neighborhoods in the fish tank look basically the same.)

The same could be said about mixtures of cultures/languages/races in the globalized world. We have lifted the partitions, and there are zones of mixing, where informational and genetic entropy is spreading. In the end, we end up with the "heat death" of humanity, where all the cultures/languages/races have been totally mixed into one uniform culture/language/race. I don't think "increasing disorder" is the right term. Disorder doesn't increase when two cultures intermix and increasingly become one culture. "Mixing" is a more value-neutral way to look at it.

The entropy concept definitely has a problem with preferred configurations, as BabyPeanut pointed out. Start out with the blue and yellow fish again, but suppose now that the fish are magnetic. The heads of the blues are attracted to the tails of the yellows, and vice versa. Now the mixing will not proceed as the mathematical concept of entropy suggests. All states are not equal. The fish will coagulate into a persistent shape, which was determined a priori by the magnetic properties of the fish. The process is deterministic, not statistical.

The biggest flaw of the 2nd Law of Thermodynamics is the formation of the seed of the Big Bang. All that energy could not focus itself into a point. To do so would be the grossest violation of the 2nd Law imaginable. Ergo, the Big Bang was impossible.
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Postby MonteQuest » Wed 30 Mar 2005, 10:52:45

$this->bbcode_second_pass_quote('smiley', 'T')he thermodynamic law is indeed statistical. The correct way to look at it is:

Every state has an equal chance of occurring. Since there are more 'disordered' states than 'ordered', a change is statistically more likely to result in a 'disordered' state than a 'ordered' one.


$this->bbcode_second_pass_quote('', 'A')ccording to this new discipline, a pile of ashes may very well become capable of heating a boiler. Also, a corpse may resuscitate to lead a second life in exactly the reverse order of the first. Only, the probabilities of such events are fantastically small. If we have not yet witnessed such "miracles," the advocates of statistical mechanics contend, it is only because we have not been watching a sufficiently large number of piles of ashes or corpses.


AND your house can spontaneously jump up, make a somersault and land on its foundations. However the odds of such an occurrence are infinitely small.

Rock hard science. 8) Yeah, I would say they are zero! But then again, maybe I need to watch more houses, corpses, and pile of ashes.

Folks, take your pick. Which would you bet your life on?
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Postby Doly » Wed 30 Mar 2005, 11:14:37

$this->bbcode_second_pass_quote('', '
')The biggest flaw of the 2nd Law of Thermodynamics is the formation of the seed of the Big Bang. All that energy could not focus itself into a point. To do so would be the grossest violation of the 2nd Law imaginable. Ergo, the Big Bang was impossible.


The concept of Big Bang is that nothing happened before the Big Bang. All that energy didn't focus itself into a point. Rather, at the beggining of time, there was a point of focused energy. Nothing made it focus.

I still can't understand why anybody would believe that the 2nd Law has any relevance to Peak Oil. The Earth isn't an isolated system. The entropy on Earth can increase. Actually, if it didn't increase, it couldn't support life.
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Postby MonteQuest » Wed 30 Mar 2005, 11:25:55

$this->bbcode_second_pass_quote('Doly', '
')I still can't understand why anybody would believe that the 2nd Law has any relevance to Peak Oil. The Earth isn't an isolated system. The entropy on Earth can increase. Actually, if it didn't increase, it couldn't support life.


Because every activity we do is governed by the 2nd law is why. How many people understand there are no free lunches? If everone understood the limits on energy constrained by 2nd Law, do you think they would still be buying the "hydrogen" economy?

And secondly, like I have reiterated so many times before, we are not concerned with the thermodynamic equillibirium with space, but the consequences of thermal inefficiency within an induction motor, for instance, or using even more complex technology as a fix-it solution that will use up the energy capital even faster due to 2nd law.
Last edited by MonteQuest on Thu 31 Mar 2005, 01:16:10, edited 2 times in total.
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Postby JohnDenver » Wed 30 Mar 2005, 11:54:41

$this->bbcode_second_pass_quote('Doly', 'T')he concept of Big Bang is that nothing happened before the Big Bang. All that energy didn't focus itself into a point. Rather, at the beggining of time, there was a point of focused energy. Nothing made it focus.


I don't buy it. No one has any evidence whatsoever on the state of the universe prior to the Big Bang. Energy appearing out of nowhere is a violation of the conservation of energy.
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Postby smiley » Wed 30 Mar 2005, 12:58:38

$this->bbcode_second_pass_quote('', 'B')ecause every activity we do is governed by the 2nd law is why. How many people understand there are no free lunches? If everone understood the limits on energy constrained by 2nd Law, do you think they would still be buying the "hydrogen" economy?


When you're talking about energy conservation you're talking about the first law, not the second. The first law is pretty straightforward:

dU = Q-W = no free lunch.

It means that you can't get work (W) done without changing the internal energy (U) or adding energy (Q). Conversely you can't get energy without work or changing the internal energy.

The first law is easy to apply in most situations but you got to acknowledge that the second law is infinately more complex.
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Postby entropyfails » Wed 30 Mar 2005, 14:48:32

$this->bbcode_second_pass_quote('JohnDenver', '')$this->bbcode_second_pass_quote('Doly', 'T')he concept of Big Bang is that nothing happened before the Big Bang. All that energy didn't focus itself into a point. Rather, at the beggining of time, there was a point of focused energy. Nothing made it focus.


I don't buy it. No one has any evidence whatsoever on the state of the universe prior to the Big Bang. Energy appearing out of nowhere is a violation of the conservation of energy.


Yeah, I have to agree JD. Big Bang requires the violation of all known physical law for about 1 second. The idea is that when you get all that matter in a small place, then laws regarding “singularitiesâ€
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Postby PenultimateManStanding » Wed 30 Mar 2005, 18:54:53

Just think how much longer it would have taken to really spread those ores out in a nice global meringue if we hadn't come on the scene. Humans are the best gradient reducers in history.
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Postby smiley » Wed 30 Mar 2005, 20:07:12

$this->bbcode_second_pass_quote('', 'P')rove to anyone that the extensive movement of minerals and hydrocarbons from an ordered (concentrated) state to a disordered (unconcentrated) state has no effect on the future of the human race


Scattering refrigerators over the earth has absolutely nothing to do with entropy. Refining iron has, manufacturing refrigerators and the their eventual decay has, but the location at which they are dumped is not thermodynamically determined.

That is exactly the problem with using the human definition of order and disorder. Because you perceive something as disordered, you assume that the entropy has changed. Because you assume that the entropy has changed you automatically assume that it is a predetermined process. That is a very fatalistic approach which leads to the idea that entropy leaves us no other option than to make a mess of things.

Of course the spread of our minerals is important for the fate of the human race, but don't blame thermodynamics. There is no entropic driving force for us spoiling our earth, no excuse, other than human sloppiness.
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