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THE Laws of Thermodynamics Thread (merged)

General discussions of the systemic, societal and civilisational effects of depletion.

Postby pilferage » Sun 19 Dec 2004, 22:21:12

I think we're missing my point (from my first point). :?
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Postby MonteQuest » Sun 19 Dec 2004, 22:37:21

$this->bbcode_second_pass_quote('pilferage', 'I') think we're missing my point (from my first point). :?



Well, you wrote this in your first post:
$this->bbcode_second_pass_quote('', 'J')ust because no one has proven them wrong so far doesn't mean they won't be proven wrong in the future. They're just extensions of mathematics used to describe our environment, and as such I don't think they can ever be proven to be consistent.


They are physical observations that have been explained by mathematics. They have been consistent enough to take us to the moon and back a few times. I don't think we need any more proof of consistency than that. And just because the laws might be shown to be somewhat wrong, someday in the future has little, if any, bearing whatsoever on current events. Why do I belabor this?
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Postby pilferage » Tue 21 Dec 2004, 03:13:57

$this->bbcode_second_pass_quote('MonteQuest', 'T')hey are physical observations that have been explained by mathematics. They have been consistent enough to take us to the moon and back a few times. I don't think we need any more proof of consistency than that.


Your arbitrary definition of consistency isn't what I was refering to. Look at my first comment... I even linked the definition I was using. The implication was also that most general concepts like the second law are usually easier to disprove then prove, because to disprove them only requires one instance where they are violated, but proving them requires that you show they are true in every case. I never knew about the experiment you mentioned, but if correct, it disproves the second law. Of course you can restructure the language of the second law, or it's application...
but that's changing it after the fact.

$this->bbcode_second_pass_quote('', 'A')nd just because the laws might be shown to be somewhat wrong, someday in the future has little, if any, bearing whatsoever on current events.


Of course it doesn't, but I'm not commenting on current events. I'm commenting on your statement that these laws aren't generalizations. They are mathematical generalizations...
and if most of our mathematical systems cannot be proven consistent, then how can our use of them to descibe our (most likely) more complex physical environment be anything more then a generalization, even if it's correct 99.99999999999999999% of the time in some arbitrary time interval, it's still a generalization.

[quoteWhy do I belabor this?[/quote]
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Keeping Chaos at Bay, 2nd Law; Part Four

Postby MonteQuest » Sat 25 Dec 2004, 12:29:09

Here's a little history and an explanation on the Second Law of Thermodynamics that I posted on another thread. I think it's worthy of a repeat here:

Sadi Carnot was a French theorist who studied the workings of the steam engine to abstract the essence of what an engine was all about. He discovered that heat energy at high temperature is capable of driving an engine and doing work. The same amount of energy at low temperature is not capable of doing useful work. The same amount of energy is still there, but something has changed. That something is what we call entropy. Carnot made an assumption that it is impossible to get something for nothing. This reasoning is what we call 2nd Law. He didn't discover the law or prove it, he just assumed it. It is an axiom whose verification lies in the fact that all predictions made on the basis of it always turn out to be true. Always, at least in the macro world that concerns us with regard to energy transfers..

2nd Law says you can't build a machine that will extract heat at low temperature and deposit that same amount of energy at higher temperature, without having any other effect. Take a refrigerator, for example. It removes heat from the food inside and dumps that energy at higher temperature into your kitchen. Here we can see entropy being decreased. But in order for your refrigerator to function, there must be another engine somewhere that is burning fuel to create heat at high temperature to create electricity to run your refrigerator. 2nd Law doesn't say heat can't be forced uphill or against a thermal gradient, but that the net effect of the power plant and your refrigerator running in tandem must always be to make heat run downhill or along the thermal gradient from high temperature to low. In other words, to run your refrigerator the power plant must always make more heat run downhill than the fridge makes run uphill. That principle is never violated. The result: an increase in overall entropy.

Gee, you say, if that is true, then you can't win! Yes, it is true, you can't. No free lunch. The principle that energy always runs from hot to cold is completely equivalent to saying entropy always increases. In an isolated system like the universe, this is a constant. In open and closed systems, like living organisms and the earth, entropy can be reversed or reduced at one point, but only with an even greater increase in entropy at another point. The rule of thumb used by engineers is that only about 1/3 of the energy in a heat source, such as a fossil fuel, can be used in another form such as electricity. Even more energy is lost when it is transmitted over power lines. So, while electric motors can be almost 100% efficient, the energy conversions required to turn a fossil fuel into electricity and transport it to power an electric motor results in only 1/3 of the energy in the fuel can be used. That is the inescapable consequence of the entropy imperative that rules the natural world.
Last edited by MonteQuest on Mon 15 Aug 2005, 00:14:41, edited 1 time in total.
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2nd Law Of Thermodynamics is Statistical

Postby BabyPeanut » Mon 21 Mar 2005, 09:41:58

From Nature and Knowledge - The philosophy of Contemporary Science By J. Bronowski, Condon Lectors, Oregon State System of Higher Education, Eugen, OR 1969 (no ISBN.)
$this->bbcode_second_pass_quote('J. Bronowski', 'I')t is often said that the progression from simple to complex runs counter to the normal statistics of chance that are formalized in the Second Law of Thermodymics. But this interpretation quite misunderstands the character of statistical laws in general. The Second Law of Thermodynamics becomes a physical law only if there is added to it the condition that there are no preferred states or configurations. In itself, the Second Law merely enumerates all the configurations which a system could take up, and it remarks that the largest number in this count are average or featureless. Therefore if there are no preferred configurations (that is, no hidden stabilities in the system) we must expect that any special feature that we find is exceptional and temporary, and will revert to the average in the long run. This is a true theorem in combinatorial artithmetic, and (like other statistical laws) a fair guess at the behavior of long runs. But it tells us little about the natural world which, in the years since the Second Law seemed exciting, has turned out to be full of preferred configurations and hidden stabilities, even at the most basic and inanimate level of atomic structure.
Last edited by Ferretlover on Mon 02 Mar 2009, 23:17:06, edited 1 time in total.
Reason: Merged with THE Thermodynamics Thread.
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Postby JohnDenver » Mon 21 Mar 2005, 10:16:59

Not sure what this has to do with peak oil, but it's a great quote, BabyPeanut!

What if you atomized yourself in a container? If a chemist looked at the gas, they wouldn't find it special in any way, and would never suspect that there was "a person in there". But there is! One of the combinations is so stable and persistent that it will actually work to maintain its own stability.

The amazing thing is that the hidden preferred state was always there, as a latent possibility within the laws governing the atoms. It reminds me of Plato's theory that we "remember" the Ideas/Forms. The idea of the "human being" was already present in the tendencies of atoms, way before human beings ever appeared on the scene. At some point, the atoms just "remembered" us.
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Re: 2nd Law Of Thermodynamics is Statistical

Postby MonteQuest » Sat 26 Mar 2005, 15:25:19

$this->bbcode_second_pass_quote('BabyPeanut', 'F')rom Nature and Knowledge - The philosophy of Contemporary Science By J. Bronowski, Condon Lectors, Oregon State System of Higher Education, Eugen, OR 1969 (no ISBN.)
$this->bbcode_second_pass_quote('J. Bronowski', 'I')t is often said that the progression from simple to complex runs counter to the normal statistics of chance that are formalized in the Second Law of Thermodymics. But this interpretation quite misunderstands the character of statistical laws in general. The Second Law of Thermodynamics becomes a physical law only if there is added to it the condition that there are no preferred states or configurations. In itself, the Second Law merely enumerates all the configurations which a system could take up, and it remarks that the largest number in this count are average or featureless. Therefore if there are no preferred configurations (that is, no hidden stabilities in the system) we must expect that any special feature that we find is exceptional and temporary, and will revert to the average in the long run. This is a true theorem in combinatorial artithmetic, and (like other statistical laws) a fair guess at the behavior of long runs. But it tells us little about the natural world which, in the years since the Second Law seemed exciting, has turned out to be full of preferred configurations and hidden stabilities, even at the most basic and inanimate level of atomic structure.


Ludwig Boltzman acknowledged the validity od 2nd Law up to a point. According to Boltzman, while it was unlikely that energy would move froim a colder to a hotter state, it was not impossible. It is important to be clear on what Boltzman was arguing because it is still taken seriously by many scientists.

Since the above quote is taken out of context and no link, I'm not sure where the writer was going with this. But from the parts I have put in bold, it would seem that while as a matter of math, it would seem that one could argue statistical 2nd law, but in the real world it doesn't hold water.

Nichloas Georgesscu-Roegen's criticism of statistical thermodynamics is worth quoting here:

$this->bbcode_second_pass_quote('', 'I')t must be admiited, though, that the layman is misled into believing in entropy bootlegging by what physcists preach through the new science known as staisitical mechanics but more adequately described as statistical thermodynamics. The very existence of this discipline is a reflection of the fact that, in spite of alll evidence, man's mind still clings with the tenacity of blind despair to the idea of an actuality consisting of locomotion and nothing else. A symptom of this idiosyncrasy was Boltzman's tragic sttruggle to sell a thermodynamics science based upon a hybrid foundation in which the rigidity of mechanical laws is interwoven with the uncertainity specific to the notion of probability....

According to this new discipline, a pile of ashes may very well become capable of heating a boiler. Also, a corpse may resuscitate to lead a second life in exactly the reverse order of the first. Only, the probabilities of such events are fantastically small. If we have not yet witnessed such "miracles," the advocates of statistical mechanics contend, it is only because we have not been watching a sufficiently large number of piles of ashes or corpses.


So, when the dead starts walking and the ashes of long dead fires heat us in the winter, then 2nd law might enter the realm of statistical. Until then, it is the supreme law of the universe.
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Re: 2nd Law Of Thermodynamics is Statistical

Postby BabyPeanut » Sun 27 Mar 2005, 19:19:42

$this->bbcode_second_pass_quote('MonteQuest', 'S')ince the above quote is taken out of context and no link,

I typed it in from a book with no ISBN. You want me to type some more?
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Postby BabyPeanut » Sun 27 Mar 2005, 19:21:53

$this->bbcode_second_pass_quote('MQ', 'S')o, when the dead starts walking and the ashes of long dead fires heat us in the winter, then 2nd law might enter the realm of statistical. Until then, it is the supreme law of the universe.

Why doesn't entropy destroy electrons? Why don't they lose charge, lose spin, gain radius or decay? Are they exempt from the second law? What kind of a law needs a qualification like "oh yeah, except for all electrons"?

Maybe it's because the 2nd Law is statistical and only applies to most things but not preferred configurations.
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Postby MonteQuest » Sun 27 Mar 2005, 19:59:35

$this->bbcode_second_pass_quote('BabyPeanut', ' ')Why doesn't entropy destroy electrons? Why don't they lose charge, lose spin, gain radius or decay? Are they exempt from the second law? What kind of a law needs a qualification like "oh yeah, except for all electrons"?

Maybe it's because the 2nd Law is statistical and only applies to most things but not preferred configurations.


If you are referring to micro quantum physics, that has only been shown to be the case for 1/10 of a second. In the macro world, which is the peak oil world we are concerned about, it changes nothing and is a moot point, no? Do you actually believe that "statistical" water may one day flow up hill and we will be able to harness the power when it flows back down to solve peakoil? Come on, BP. Why else muddy the waters here?
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Postby Jack » Sun 27 Mar 2005, 20:26:28

$this->bbcode_second_pass_quote('BabyPeanut', '
')Why doesn't entropy destroy electrons? Why don't they lose charge, lose spin, gain radius or decay? Are they exempt from the second law? What kind of a law needs a qualification like "oh yeah, except for all electrons"?

Maybe it's because the 2nd Law is statistical and only applies to most things but not preferred configurations.


But do we know it doesn't? The question has been asked (but not yet answered) - do fundamental particles such as the proton or electron decay?

Then there's another issue - what, exactly, is an electron? Is it a particle, or a wave? In the two-slit experiment, it acts like a wave - but if we detect which slit it goes through, the wave function collapses, and it behaves like a particle.

And then you get into such debates as whether fundamental constants of the universe, such as the speed of light change. Some contend that red shift is not entirely due to expansion, but rather to entropy affecting light itself.

So, I guess my reaction is...great question! There's probably a Nobel prize in physics for whoever gets the answer. 8)

In the meantime, you might enjoy reading something about time, entropy, and the universe here:

Part I: The Intrinsic Motion of Time, Space, and Gravity
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Postby BabyPeanut » Mon 28 Mar 2005, 07:26:23

$this->bbcode_second_pass_quote('Jack', 'd')o fundamental particles such as the proton or electron decay?

Fundamental particles such as the proton? :lol: :lol: :lol:
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Postby BabyPeanut » Mon 28 Mar 2005, 10:20:17

$this->bbcode_second_pass_quote('MonteQuest', 'I')f you are referring to micro quantum physics, that has only been shown to be the case for 1/10 of a second.

References?
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Postby Jack » Mon 28 Mar 2005, 11:20:42

$this->bbcode_second_pass_quote('BabyPeanut', '')$this->bbcode_second_pass_quote('Jack', 'd')o fundamental particles such as the proton or electron decay?

Fundamental particles such as the proton? :lol: :lol: :lol:


So, you're looking at quarks or even strings, I suppose - but if we can't deal with protons, are we ready to do useful work with the others?
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Postby MonteQuest » Mon 28 Mar 2005, 11:30:46

$this->bbcode_second_pass_quote('BabyPeanut', '')$this->bbcode_second_pass_quote('MonteQuest', 'I')f you are referring to micro quantum physics, that has only been shown to be the case for 1/10 of a second.

References?


Hmm...I guess you haven't read my posts on 2nd law.

$this->bbcode_second_pass_quote('', 'T')he Second Law of Thermodynamics says that the disorder of the Universe can only increase in time, but the equations of classical and quantum mechanics, the laws that govern the behaviour of the very small, are time reversible. A few years ago, a tentative theoretical solution to this paradox was proposed - the so-called Fluctuation Theorem - stating that the chances of the Second Law being violated increases as the system in question gets smaller.

This means that at human scales, the Second Law dominates and machines only ever run in one direction. However, when working at molecular scales and over extremely short periods of time, things can take place in either direction. Now, scientists have demonstrated that principle experimentally. Professor Denis Evans and colleagues at the Research School of Chemistry at the Australian National University put 100 tiny beads into a water-filled container. They fired a laser beam at one of the beads, electrically charging the tiny particle and trapping it.

The container holding the beads was then moved from side to side a thousand times a second so that the trapped bead would be dragged first one way and then the other. The researchers discovered that in such a tiny system, entropy can sometimes decrease rather than increase. This effect was seen when the researchers looked at the bead's behaviour for a tenth of a second. Any longer and the effect was lost.
This is the only known experiment that I am aware of. Care to share yours? Disproving 2nd Law consistency for a tenth of a second does not hold much hope for me in solving the issue of peak oil. And in this experiment, it seems that shaking the container was adding kenetic energy to the closed system. False results? Dunno...In our peak-oil macro world, 2nd Law cannot be questioned, nor is it.
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Postby BabyPeanut » Mon 28 Mar 2005, 11:37:01

$this->bbcode_second_pass_quote('Jack', '[')So, you're looking at quarks or even strings, I suppose - but if we can't deal with protons, are we ready to do useful work with the others?

The electron is a fundemental particle. The proton is not.
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Postby BabyPeanut » Mon 28 Mar 2005, 11:42:17

$this->bbcode_second_pass_quote('MonteQuest', 'D')isproving 2nd Law consistency for a tenth of a second does not hold much hope for me in solving the issue of peak oil.

I'm not trying to disprove the 2nd Law. I'm trying to understand it. How can human bodies exist along with entropy? How can a star start out with hydrogen and make iron? How can that iron end up in the hemoglobin in my blood? How can something so blatently and repeatedly fly in the face of entropy for so much time?
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Postby MonteQuest » Mon 28 Mar 2005, 12:12:38

$this->bbcode_second_pass_quote('BabyPeanut', ' ')I'm not trying to disprove the 2nd Law. I'm trying to understand it. How can human bodies exist along with entropy? How can a star start out with hydrogen and make iron? How can that iron end up in the hemoglobin in my blood? How can something so blatently and repeatedly fly in the face of entropy for so much time?


As far as human bodies are concerned, it is called non-equillibrium thermodynamics. I have covered this at length on other threads. Basically the body holds entropy at bay with a constant flow-thru of energy and matter. We are an open system. Once this flow thru ends, we die and entropy acclerates and we rot. There is no mystery here, nor a contradiction to 2nd Law.

As to your other points, I'm not sure why you think that is counter to 2nd law.
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Postby BabyPeanut » Mon 28 Mar 2005, 23:14:13

The point is that evolution decreases entropy.
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Postby MonteQuest » Mon 28 Mar 2005, 23:23:32

$this->bbcode_second_pass_quote('BabyPeanut', 'T')he point is that evolution decreases entropy.


How so? I just explained how it does not.
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