by Graeme » Tue 27 Nov 2012, 15:38:05
Nanotechnology simplifies hydrogen production for clean energy
$this->bbcode_second_pass_quote('', 'I')n the first-ever experiment of its kind, researchers have demonstrated that clean energy hydrogen can be produced from water splitting by using very small metal particles that are exposed to sunlight. In the article, "Outstanding activity of sub-nm Au clusters for photocatalytic hydrogen production," published in Applied Catalysis B: Environmental, Alexander Orlov, PhD, an assistant professor of materials science and engineering at Stony Brook University, and his colleagues from Stony Brook and Brookhaven National Laboratory, found that the use of gold particles smaller than 1 nm resulted in greater hydrogen production than other co-catalysts tested.
"This is the first ever demonstration of the remarkable potential of very small metal nanoparticles [containing fewer than a dozen atoms] for making fuel from water," says Orlov. Using nanotechnology, Orlov's group found that when the size of metal particles are reduced to dimensions below 1 nm, there is a tremendous increase in the ability of these particles to facilitate hydrogen production from water using solar light. They observed a "greater than 35 times increase" in hydrogen evolution as compared to ordinary materials.
rdmagLight-based hydrogen production $this->bbcode_second_pass_quote('', 'A') group of chemists at the University of Rochester has succeeded in increasing the output and lowering the cost of current light-driven hydrogen production systems. The paper based on the work, which was led by the chemistry professors Richard Eisenberg, Todd Krauss and Patrick Holland, has been published in the journal Science.
One disadvantage of current methods of hydrogen production is the lack of durability. The Rochester scientists were able to overcome that problem by incorporating nanocrystals. Generally, organic molecules are used to capture light in photocatalytic systems. “The problem is that,” Krauss points out, “they only last hours, or, if you’re lucky, a day. These nanocrystals performed without any sign of deterioration for at least two weeks.”
Systems used over the last decades by Eisenberg typically generated 10,000 instances—called turnovers—of hydrogen atoms being formed without needing to have any component replaced. With the nanocrystals, the researchers witnessed turnovers in excess of 600,000. Further, the present work used a catalyst made from nickel, which is more easily available, more affordable, and lower in toxicity compared with expensive metals such as platinum.
The work is still in the “basic research stage”, making it impossible to provide cost comparisons with other energy-production systems. Currently, nickel costs about $8 a pound (1 lb is 0.454 kg) and platinum costs $24,000 a pound.
While the commercial implementation of their work is years off, Holland points out that an efficient, low-cost system will have uses beyond energy. “Any industry that requires large amounts of hydrogen would benefit, including pharmaceuticals and fertilizers,” he says.