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THE Thermal Depolymerization Thread (merged)

Discussions of conventional and alternative energy production technologies.

Re: Why won't TD plants work?

Unread postby scareduck » Sun 19 Dec 2004, 21:47:03

$this->bbcode_second_pass_quote('0mar', 'I') know they can't be scaled up in time or ever really, nor can they recycle everything.

However, at a forum I visit, people seem to cling onto this as the last savior (along with fusion). I have been formulating some sort of rebuttal but it doesn't look as solid as it can be.

So far I have:

1. TD needs electricity, which requires gas/coal. Gas is plateau, and coal could be useless by 2040 if the current decline in EPR continues.

The process generates its own fuel gas which is used to run the plant, thus claims that the process front to back is 85% efficient. It does not run off the grid.
$this->bbcode_second_pass_quote('', '
')3. TD can only produce oil from wastes, which will turn into products and back into waste. Because of the 2nd law, we will be getting diminishing returns.

What if some other feedstock were used (crops, algae grown at sea, etc.)?
$this->bbcode_second_pass_quote('', '
')4. All oil isn't equal, and TD has very few scientific studies (that I have found at least) done on it regarding the quality and quantity truly obtained.

This is sort of saying you don't know, either.
$this->bbcode_second_pass_quote('', '
')5. Producing TD plants is expensive and a massive overhaul will costs time, money and tons of oil, for what amounts to a high tech recycling unit.
6. There is only one TD plant operating in the US and its profitability remains to be seen.

These are probably the single biggest charges: TD is at best a recycling effort, unless scaled very, very large. The economics of such activities remains to be seen. At present, it is, at most, a nice way for ADM to clean up hog ponds and turkey entrails. But, see also my comment above; there's no reason we couldn't find some biotic feedstock for it. Of course, the current scale of the transportation uses of oil would make it very difficult to replace as much as we presently use, let alone would use in the future.

$this->bbcode_second_pass_quote('', '
')7. Oil operations are on a scale that we can barely comprehend. After a while, numbers start looking the same, but as it stands, TD is only a bit player in the world of oil and probably will always be a bit player in the grand scheme of things.


I think that depends on the size of oil consumption, don't you? :-)

TDP could have other uses, such as reducing heavy oil to lighter grades, or converting coal to petroleum. Whether those activities are EROEI effective remains a speculative exercise.
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Unread postby Guest » Fri 07 Jan 2005, 04:58:29

this doesn't make sence to me at all.

When it gets even remotely close to having to tap the turkey-biodiesel to make more turkeys, it's all over. [I]


Why?


if i have turkey biodiesel...and have to use some of it to make more turkeys, why would it "all be over" that is plain stupid.


turkeys eat, shit , and breed. we aren't talking about extracting oil from the ground with more oil here, we are talking about harvesting a natural food source's byproduct (waste) and converting it into fuels.
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Unread postby Cash » Fri 07 Jan 2005, 10:18:57

I think the important thing to remember about TDP is that it's basically just a recycling operation. We put our newspapers and tin cans out to be recycled. The TDP folks are doing the same with other parts of the waste stream. More power to them, but it's not a cure-all. It's just a way of getting out some of the energy we have already put into a product, whether it's a plastic jug or a turkey.

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Unread postby Aaron » Fri 07 Jan 2005, 10:39:45

Also important to remember that when considering any energy source including recycling, just how high a peak do we want to drop from?

It's not as if recycling or conservation energy savings go into some "energy bank" for future generations, but simply allows humanity to further increase our global energy profile.
The problem is, of course, that not only is economics bankrupt, but it has always been nothing more than politics in disguise... economics is a form of brain damage.

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TDP

Unread postby pup55 » Fri 07 Jan 2005, 11:31:13

http://peakoil.com/fortopic505.html

We have been following this for awhile.

The CWT website has recently been updated: a lot of the technical papers have been removed (no doubt to keep people like us from analyzing them), and also, there is a link to the JV with Con Agra. No word on how they are dealing with the odor problems coming from the plant, or even how well the plant is running.

The character R James Woolsey has emerged again recently. This fellow was the former CIA director under Clinton, and frequent talking head on CNN. For awile, he was a paid "military affairs consultant" for CWT. It appears his main function was a lobbying-type role to open doors for government grants, etc.

Woolsey made a presentation the other day at the conference at the US Capitol on the importance of biofuels as they relate to national security.

He is no longer listed as part of the management of CWT, interestingly, but maybe they have already opened all the doors they need. He is quoted in one of their press blurbs.

Gotta keep an eye on him, too.
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TD

Unread postby Optimist » Tue 15 Feb 2005, 21:29:39

$this->bbcode_second_pass_quote('', '3'). TD can only produce oil from wastes, which will turn into products and back into waste. Because of the 2nd law, we will be getting diminishing returns.


This is TD's claim to fame. Things that we currently have no use for (aka trash, sewage sludge, agri waste, etc.) has the potential to replace crude. Since we will always produce waste, this means TD will never run out of feedstock. The diminished returns you refer to will be made up with energy from the sun, by a well known process called photosynthesis.

Instead of eating 1 - 10% of our agricultural produce and letting the rest rot in landfills, we will be using the remaining 90 - 99% to produce fuel. I suggest that this is as close to sustainable as we would be able to go.

BTW, TD is Thermal Depolymerization (as in using heat to break polymers down into monomers), not Thermo Depolarisation!
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Unread postby Cash » Thu 17 Feb 2005, 17:51:49

TDP, as thermodepolymerization is often called, is basically just a recycling program, not unlike recycling newspaper and tin cans. Assuming it works as advertised, it sounds like a great way to squeeze another cycle of productive use out of waste materials, from municipal garbage to old computers. I've read that it can even process municipal sewage into oil and fertilizer, as well as producing natgas and pure water.

But it is just recycling. It needs an initial supply stream, and I haven't seen the numbers that support the idea that it can be anything more than a nice supplement to oil requirements, not a huge savior.

I believe that post-Peak we will see major decentralization in energy sources to a much more locally produced model -- wind, solar, PV, biodiesel, ethanol, wood-fired generating station, horses, mini-hydro, and things like TDP. Nothing is going to provide the silver bullet, but there's no reason TDP can't be part of the larger mix.

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TDP

Unread postby Optimist » Thu 17 Feb 2005, 21:08:29

$this->bbcode_second_pass_quote('', 'I') haven't seen the numbers that support the idea that it can be anything more than a nice supplement to oil requirements, not a huge savior.

Let's talk about numbers then. According to Changing World Technologies (CWT http://changingworldtech.com/what/problems.asp#energy ), the inventor of TDP, there is enough agricultural waste (6 billion tons/year) in the US to replace all oil imports. Using all solid waste produced in the US (12 billion tons/year) could yield 24 billion bbl/year, compared to a demand of ~ 19 billion bbl/year in 1998.

Even if CWT are lying through their teeth and the process is only 20 - 25% as effective as they claim, it still has the potential to be very significant.
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Re: TDP

Unread postby 0mar » Thu 17 Feb 2005, 22:10:41

$this->bbcode_second_pass_quote('Optimist', '')$this->bbcode_second_pass_quote('', 'I') haven't seen the numbers that support the idea that it can be anything more than a nice supplement to oil requirements, not a huge savior.

Let's talk about numbers then. According to Changing World Technologies (CWT http://changingworldtech.com/what/problems.asp#energy ), the inventor of TDP, there is enough agricultural waste (6 billion tons/year) in the US to replace all oil imports. Using all solid waste produced in the US (12 billion tons/year) could yield 24 billion bbl/year, compared to a demand of ~ 19 billion bbl/year in 1998.

Even if CWT are lying through their teeth and the process is only 20 - 25% as effective as they claim, it still has the potential to be very significant.


Let's work the math.

Let's assume TD can cover our imports. That's ~13 million barrels per day. At 1,000 bpd per plant, we would need 1,000 plants. So 13 million barrels will need 13,000 plants. Bringing this online in 15 years would require 2.5 plants being built daily (365 x 15 = 5475, 13,000 / 5475 = 2.38....). TD is viable at a technical level only, not on an economic level.
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TDP

Unread postby Optimist » Fri 18 Feb 2005, 13:54:08

$this->bbcode_second_pass_quote('', 'A')t 1,000 bpd per plant, we would need 1,000 plants. So 13 million barrels will need 13,000 plants. Bringing this online in 15 years would require 2.5 plants being built daily (365 x 15 = 5475, 13,000 / 5475 = 2.38....). TD is viable at a technical level only, not on an economic level.


You're joking, right? There is no reason why the size of the plant would be limited to 1,000 bpd. The MO plant is sized for 500 bpd because that is what they expect to make from the 200 t/d of available waste. If, for example, you wanted to treat all of New York City's waste with TDP you would build one big plant and realize the benefit of scale, not multiple small units.

The economics of TDP depends mainly on the price of crude.
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Re: TDP

Unread postby eric_b » Fri 18 Feb 2005, 15:24:05

$this->bbcode_second_pass_quote('Optimist', '')$this->bbcode_second_pass_quote('', 'A')t 1,000 bpd per plant, we would need 1,000 plants. So 13 million barrels will need 13,000 plants. Bringing this online in 15 years would require 2.5 plants being built daily (365 x 15 = 5475, 13,000 / 5475 = 2.38....). TD is viable at a technical level only, not on an economic level.


You're joking, right? There is no reason why the size of the plant would be limited to 1,000 bpd. The MO plant is sized for 500 bpd because that is what they expect to make from the 200 t/d of available waste. If, for example, you wanted to treat all of New York City's waste with TDP you would build one big plant and realize the benefit of scale, not multiple small units.

The economics of TDP depends mainly on the price of crude.


I think the gist of Omar's argument is correct. You don't seem
to fully understand the magnitude of the problem. I can see TD
playing a minor role as an alternative energy source - say in line
with solar/wind/hydro (a few percent of total) but there's no way
it's ever going to replace most of the oil we currently use.

Don't make me throw more numbers at you.
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Unread postby 0mar » Fri 18 Feb 2005, 16:33:45

The most optimistic of sites say that TD plants can have a capacity of 1,000 bpd.
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Very convincing

Unread postby Optimist » Fri 18 Feb 2005, 19:29:22

That's very convincing guys!
$this->bbcode_second_pass_quote('', 'D')on't make me throw more numbers at you.

Throw! I may even hit it over the fence.

$this->bbcode_second_pass_quote('', 'T')he most optimistic of sites say that TD plants can have a capacity of 1,000 bpd.

Based on what? There is no reason to limit it to 1,000 bpd.
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Unread postby 0mar » Fri 18 Feb 2005, 22:54:56

Because that is the inherent limitation of the technology.

Things just can't scale up to something convienant.
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Unread postby RdSnt » Sat 19 Feb 2005, 19:36:26

Let's look at this in a much more basic way.

Assume for a moment that fossil oil took 1billion years to create. I just using a nice round number. There was a certain amount of energy expended to create that fossil oil. From year to year though the amount was very small.

In our present circumstances, we want to convert waste material into oil. However we don't want to wait a billion years, we need to accelerate the conversion process. Acceleration requires additional energy. In the end we don't have enough energy to convert the waste to oil in any type of positive EROEI calculation.

Also keep in mind some products, such as plastic, require much more energy to break down than it took to create the origin component from fossil fuel resources. Also it is good to keep in mind that we don't calculate the cost of the making of fossil fuel in our estimates for making a product. We should.
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Unread postby nero » Sat 19 Feb 2005, 20:56:03

One factor to consider with TD is that the quality of the trash is important. Not just the energy content but the contamination. If the waste is homogenous and reliably contamination free then you're golden but what happens if you start throwing in real trash, then you will get oil contaminated with heavy metals that would be dangerously polluting.

Another consideration is that agricultural waste often isn't. It's fertilizer.

A third consideration is that waste is dispersed. If it must be trucked to a central TD processing unit to achieve the efficiencies of scale, that aslo is a significant cost.
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Unread postby 0mar » Sat 19 Feb 2005, 23:41:42

$this->bbcode_second_pass_quote('RdSnt', 'L')et's look at this in a much more basic way.

Assume for a moment that fossil oil took 1billion years to create. I just using a nice round number. There was a certain amount of energy expended to create that fossil oil. From year to year though the amount was very small.

In our present circumstances, we want to convert waste material into oil. However we don't want to wait a billion years, we need to accelerate the conversion process. Acceleration requires additional energy. In the end we don't have enough energy to convert the waste to oil in any type of positive EROEI calculation.

Also keep in mind some products, such as plastic, require much more energy to break down than it took to create the origin component from fossil fuel resources. Also it is good to keep in mind that we don't calculate the cost of the making of fossil fuel in our estimates for making a product. We should.


The EROEI is always going to be negative for TD because you are synthesizing the energy products. We just are converting something that wouldn't have normally been energy into energy.
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Unread postby FrankRichards » Sun 20 Feb 2005, 18:55:17

Omar,

Would you please post a reference that explains why a TDP plant can't be scaled?

And I can't avoid the feeling that when you're talking about waste, EROEI calculations on just the waste are all bogus. You need to get rid of the stuff and that cost is part of the EREOI of what you really wanted to do, which I expect is never to just make a pile of waste. So for the extant case of turkey guts, the issue is "does using TDP to rid of the offal improve the EREOI of raising turkeys by 'conventional' means?" I haven't seen any claim by anyone that implies that it doesn't.

The PITA is that you have to look at each waste stream individually. I'm sure that TDP is better than say landfilling feedlot manure, but it's less clear that you can't get a better return using a conventional methane digester, and then either TDPing or just using the (much smaller now) residue for fertilizer.
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Unread postby Licho » Sun 20 Feb 2005, 20:12:16

There is probably no real obstacle in sizing the plants or even building enough of them in few decades.. There is also no problem with powering these plants, as they casn use their own produced methane to power self.
What I see as an obstacle is stealing the energy from ecosystem. If you treat all biological waste this way, you are certainly not going to return it back to ecosystem (as fertilizer and base for next generation of plants/animals) but instead throw it into atmosphere as CO2. But ecosystem is where it belongs. If you remove tonnes of biological material from it, then you need to use tonnes of synthetic fertilizers and other stuff to "refill" organic base for plants. You can't increase efficiency of primary energy source (which is photosynthesis) this way for longer period, if you do, you are stealing from organic base and reducing fertility of land. You can only come as close as possible to photosynthetic efficiency limit with tdp. If we are now using 1/5 or 1/10 of energy provided by plant photosynthesis, using this process we could come closer to 100%, but we cannot go beyond it.. we cannot surpass limits of plants which actually capture this energy from sun with this technology.

If we put it this way, then the question is not how many TDP do we need to construct, but rather:
How large area of farmland do we need to capture enough energy from sun to power society.
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Unread postby nocar » Mon 21 Feb 2005, 11:54:31

To give a hint on the scaling potential, let's look at Stockholm, Sweden

We have a very great sewage treatment system, and it actually produces biogas for running buses (aside from treating the sewage).

Shit and toilet paper from a million people now power about ten buses.
That's it. All the thousands other buses and about 300.000 cars and xx thousand trucks just have to sit still if we would have to rely on this sources of waste for powering motor vehicles. (We have electric trains and subways that can keep running on nuclear and hydro like they do today)

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