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THE Thermal Depolymerization Thread (merged)

Discussions of conventional and alternative energy production technologies.

Re: Too good to be true? or not?

Postby Aedo » Mon 12 Sep 2005, 04:29:33

There is more than one answer to any question - especially when the question is as complex as PO!

The obvious now stated :) there are lots of ways to better utilise current resources (including waste) - this has potential to deliver a useful product but as Starvid has pointed out there is just not enough information available as yet. It will be interesting to see if the process is profitable in both EROEI and economic terms.
Last edited by Aedo on Mon 12 Sep 2005, 22:03:17, edited 1 time in total.
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Re: Too good to be true? or not?

Postby aahala » Mon 12 Sep 2005, 13:47:01

I thoght they had shut down the plant because the costs were greater than
what they could sell the product for.

The citizens of Carthage created a stink over the stink of the plant and
the State of MIssouri(finally) stepped in a while back. I'm sure if you google something like "Carthage,MO" and "smell" you'll get dozens if not
hundreds of hits about the odor. It apparently was really, really bad.
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Re: Too good to be true? or not?

Postby strider3700 » Mon 12 Sep 2005, 15:21:42

this is thermal depolymerization(sp) correct? If so my understanding was to be at all efficient they needed a consistant feedstock which is ok in some cases but you can't just dump massive amounts of garbage into it and get back oil. the costs kept it above $60/barrel produced as well if I remember correctly.
shame on us, doomed from the start
god have mercy on our dirty little hearts
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Re: Too good to be true? or not?

Postby Googolplex » Mon 12 Sep 2005, 15:25:33

This is not new. Its TDP, except called TCP instead.

While this could serve as a minor source of oil in the future, it still requires more energy to run it then it produces.

Personally, I think we should focus on ways to use LESS energy, not ways to increase our energy useage like this. Instead of sucking tons more power from the electric grid, lets just reduce the amount of oil we need.
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Re: Too good to be true? or not?

Postby BrownDog » Mon 12 Sep 2005, 15:49:29

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Re: Viable way of getting oil from shale

Postby Googolplex » Mon 12 Sep 2005, 15:59:11

$this->bbcode_second_pass_quote('Optimist', 'Y')ou know nothing about power generation, do you? A coal power plant converts between 15 and 20% of the energy in the coal to electricity. Compared to that 85% capture is staggering.


Wow. Ive never seen such an example of flinging numbers around that one doens't understand. Sorry about the lateness of my reply BTW.

The total EROEI of coal is not 15-20%. According to the figures Ive found, its somewhere around 30:1, or 3000%, and that includes the 15-20% efficiency of burning it. Compare that to the 85% of TDP!

You see, the energy in coal, or oil, or any fossile fuel, is already there, ready for use. We don't have to "invest" it. We only need to transport it to where we need it and burn it (or do whatever). Thats why its a source of energy.

Now, we COULD then turn around and take all that energy we get from the coal and use it for TDP, but the oil and gas we get back out would only equal 85% of the energy invested, which itself is only 15-20% of the energy in the coal. So if you have a TDP plant powered by coal, for every 1 unit of energy in coal that you consume, you get only 13-17% back, or somewhere around 0.1275 and 0.17 units back.

Coal liquification would be a MUCH better idea.

$this->bbcode_second_pass_quote('', 'N')ote that the only electricity needed to operate the plant is about 3.6% of the energy produced by TDP, and that is only counting the oil. I believe that is an ERoEI of 99.5/3.6 = 27.6. Way bigger than 1.0 you will be glad to know. See Figure 6, p8 at http://www.itcnet.org/Fire%20web%20site ... rocess.pdf


See sentance 1 page 9. The efficiency of the process is indeed 85%, which is less then 100%, or an EROEI of less then 1. It is NOT an energy source. That company knows this and specifically states it in the paper you sited, why won't you except it?
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Re: Too good to be true? or not?

Postby sicophiliac » Tue 13 Sep 2005, 01:50:43

Plant produces 500 barrels of oil a day, wow.. wed only need 10,000 of them to really make a dent in oil supply.
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Re: Too good to be true? or not?

Postby Bluster » Tue 13 Sep 2005, 08:26:29

Thank you for having my hopes dashed to pieces once again :cry: :P 8O :( :(
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Add one more to the 101 uses for a dead cat

Postby bruss01 » Wed 14 Sep 2005, 14:35:30

http://www.cnn.com/2005/WORLD/europe/09 ... index.html

Sounds like a Thermal Depolymerization type thing. Guy claims to run his car on them.
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Re: Add one more to the 101 uses for a dead cat

Postby Carrie » Wed 14 Sep 2005, 14:48:32

They say that the exhaust from cars that run on vegetable oil smells like french fries. I wonder what dead cat exhaust would smell like? :twisted:
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Re: Add one more to the 101 uses for a dead cat

Postby Optimist » Wed 14 Sep 2005, 15:05:25

This is a great business opportunity for all PeakOilers: For the low-low cost of US$4 million you could be producing diesel for 0.24 Euro/liter [US$48/bbl], see http://www.transgasindustry.ru/diz2.shtml. Just think of the profits you will make when PO "hits".

Note the plant does not run on dead cats only, that was just a nice publicity stunt by Bild. "Capability: All Bio Mass" - http://www.globalfinest.com/tech/

Nice to see the waste to oil business is taking off, right in the nick of time.
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Re: Add one more to the 101 uses for a dead cat

Postby Googolplex » Wed 14 Sep 2005, 15:07:39

Rest easy animal lovers! It should run just as well on dead people too! :-D
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Re: Thermal Depolymerisation Process

Postby Optimist » Wed 14 Sep 2005, 15:13:26

I notice that the new German invention (cats to diesel, if you fall for Bild's publicity stunt, see http://www.msnbc.msn.com/id/9339530/ ), KDV 500, see http://www.globalfinest.com/tech/ shows many similarities to TDP:
1. Claims ability to convert any organic waste "Capability: All Bio Mass" into diesel (including carbohydrate).
2. High efficiency "Efficiency level: 70% - 94%", typical "The plant’s high efficiency (~80%)" compared to TDP's 85%.
3. Sounds like TDP "Molecular depolymerization at low temperatures (270 – 350°C) and virtually pressure-free (< 0.1bar)" compared to TDP's first stage 200 - 300°C and 35 - 48 bar.
4. Economics: "Total Manufacturing costs per litre of diesel oil: approx. 50 c/l" at "The plant offered has a 500+ Ltr/hr [75 bbl/d] output capacity." Another reference, http://www.transgasindustry.ru/diz2.shtml puts the production cost @ 0.238 Euro/L or US$48/bbl at 1,000 L/h or 150 bbl/d. That's pretty close to the $60-65/bbl CWT's Carthage facility would be doing if they did not have to pay for the waste.
5. Even the graphic at the top of the page looks erily similar to CWT's webpage.

Key difference: This process requires a reletatively dry input: "Input Moisture Content Required: < 4 %" which puts TDP still in front as far as many wastes are concerned.

Nice to see waste to oil technologies taking off in the nick of time...
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Re: Too good to be true? or not?

Postby Optimist » Wed 14 Sep 2005, 15:39:27

Don't despair, Bluster. Waste to oil technologies are taking off just in the nick of time. Could you think of a better future fuel than waste? I can't. Notice that the Germans have developed a similar process, called KDV 500 - see http://www.globalfinest.com/tech/

Also note that no breaking of thermodynamic laws are required. "The total global energy use in 1995 was 383 EJ. For comparison, about 5.5 million EJ of sunlight strikes the upper atmosphere of the Earth each year, and about 250,000 EJ of that makes it to Earth's surface. So humans used the equivalent of less than 0.2% of the Sun's energy striking the Earth's surface in 1995." - http://www.cpast.org/Articles/fetch.adp?topicnum=13

I tend to think we will come up with a way to collect more than 0.2% of the sun's energy before oil, coal, natural gas and uranium runs out. And, of course, we will always have waste.
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Re: Add one more to the 101 uses for a dead cat

Postby frost667 » Wed 14 Sep 2005, 15:48:28

$this->bbcode_second_pass_quote('Googolplex', 'R')est easy animal lovers! It should run just as well on dead people too! :-D


If things go really bad there will be much more dead humans than dead cats, I suppose...
But thanks for your input, it made me smile.
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Re: Too good to be true? or not?

Postby Googolplex » Wed 14 Sep 2005, 15:50:41

$this->bbcode_second_pass_quote('Optimist', 'D')on't despair, Bluster. Waste to oil technologies are taking off just in the nick of time. Could you think of a better future fuel than waste?


Note, of course, that this is NOT using waste as fuel, like with incinerators and such. This is using waste as raw materials to produce fuel. It still consumes more energy from our available reserves to convert that waste then it produces as oil. Assuming we have the spare energy available from coal or renewables to support it, this could be a valuble way to suppliment oil supplies in the short term, but its no solution unless we suddenly discover cold fusion or somthing.
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Re: Add one more to the 101 uses for a dead cat

Postby MacG » Wed 14 Sep 2005, 16:55:17

Well, everything seem to hinge on those 'catalysts'. If they are true, the thing might stick together. Otherwise it could be a fraud involving a chemical engineer. Otherwise, classic TD followed by Fisher-Tropsch is not bad, and if you stop earlier than F-T and rest with dimethylether you get even better efficiency.
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Re: Too good to be true? or not?

Postby Optimist » Wed 14 Sep 2005, 17:23:31

$this->bbcode_second_pass_quote('', 'I')t still consumes more energy from our available reserves to convert that waste then it produces as oil.

Excuse me, but you are talking through your nose. Now, I suspect the energy balance in the following link: Click . see Figure 6 on page 8 is out of date and not 100% accurate. As the best available information on TDP it would have to do, though.

Energy input (as electricity): 3.6 MM BTU/h. Energy output (as TDP 40 oil, ignoring other output): 99.5 MM BTU/h. ERoEI = 99.5/3.6 = 27.6!

$this->bbcode_second_pass_quote('', 'N')ote, of course, that this is NOT using waste as fuel, like with incinerators and such.

This statement is almost too absurd to respond to. You put in 122.9 BTU/h (as waste) and 3.6 MM BTU/h as electricity for a total energy input of 126.5 MM BTU/h. The 85% efficiency means that 126.5 x .85 = 107.5 MM BTU/h comes out as useful products, the difference, 19 MM BTU/h is used to power the process, mainly to heat in the feedstock to the required temperatures.

Check Figure 6 again. A fraction of the 99.5 MM BTU/h of oil can be used to generate the 3.6 MM BTU/h of electricity. This would make the process self-sufficient and an ENERGY PRODUCER.
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Re: Too good to be true? or not?

Postby scordry » Wed 14 Sep 2005, 17:58:36

This sort of operation gives me the same question as that of ethanol plants:

I'll be really convinced of their positive energy production capabilities once someone uses the ethonal produced in the plant to actually plant, fertilize, harvest and transport corn to the ethanol plant. How much ethanol would they have as surplus that could be used for non-ethanol production? (Of course, the employees would need to have E85 cars.)

But any process that converts garbage (or sewage even) into energy will ultimately be a loser because they depend on the copius amounts of rubbish produced by a consumer-driven society. When this large storehouse of energy (i.e., the trash) is no longer produced at great rates, these kinds of energy producing operations will not be feesable.

We'll be talking about Peak Garbage.

:roll:
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