by Devil » Sun 05 Sep 2004, 11:14:19
Being my own devil's advocate, I understand what he is saying, but I cannot imagine 100% recovery for several reasons:
1. there will be capillary retention of oil in rock pores.
2. hydrogen bonds are very difficult to break and require energy to do so: there will be bonding between the oil and the rock.
3. if there has been emulsification between oil and natural or injected water, micellar bonding, forming a hydrophilic monolayer with high-density van der Waal's packing between HC molecules could occur over the whole rock surface (see Rao's Surface Phenomena). Although molecularly thin, the high density and the massive surface area of the porous rock could retain vast quantities.
4. the experiments were conducted with acrylic beads, to simulate the porous rock, and gear oil. These conditions do not even remotely resemble crude oil in rock, especially as gear oil is not as thixotropic as crude.
5. the patent was applied for 50 years ago, so the technique must now be in the public domain. If it were as effective as the author claims, surely it would be in popular use?
Devil